675608-06-7

Basic information

• Product Name: Carbonic acid, methyl (2E)-3-(4-nitrophenyl)-2-propenyl ester
• CAS NO: 675608-06-7
• Molecular Formula: C11H11NO5
• Molecular Weight: 237.212
• Mol File: 675608-06-7.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Carbonic acid, methyl (2E)-3-(4-nitrophenyl)-2-propenyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Carbonic acid, methyl (2E)-3-(4-nitrophenyl)-2-propenyl ester(675608-06-7)
• EPA Substance Registry System: Carbonic acid, methyl (2E)-3-(4-nitrophenyl)-2-propenyl ester(675608-06-7)

Safety Data

• Hazardous Substances Data: 675608-06-7(Hazardous Substances Data)

Upstream product

• 35271-56-8 (E)-4-nitrocinnamyl alcohol 
• 79-22-1 methyl chloroformate 
• 555-16-8 4-nitrobenzaldehdye 
• 24393-61-1 ethyl (E)-3-(4-nitrophenyl)-2-propenoate 

Downstream Products

• 1304683-85-9 (2S,3S)-tert-butyl 2-cyano-2-ethyl-3-(4-nitrophenyl)pent-4-enoate 
• 1440140-73-7 (E)-dimethyl 2-(3-(4-nitrophenyl)allyl)-2-(trifluoromethyl)malonate 
• 1440140-54-4 (E)-methyl 5-(4-nitrophenyl)-2,2-bis(trifluoromethyl)pent-4-enoate 
• 1239597-54-6 ethyl (2E,4E)-2-benzylidene-5-(4-nitrophenyl)pent-4-enoate 
• 1239597-45-5 (E)-ethyl 2-methylene-5-(4-nitrophenyl)pent-4-enoate 

Relevant articles and documents

Stereodivergent Allylation of Azaaryl Acetamides and Acetates by Synergistic Iridium and Copper Catalysis

We report stereodivergent allylic substitution reactions of allylic esters with prochiral enolates derived from azaaryl acetamides and acetates to form products from addition of the enolates at the most substituted carbon of an allyl moiety with two catalysts, a chiral metallacyclic iridium complex and a chiral bisphosphine-ligated copper(I) complex, which individually control the configuration of the electrophilic and nucleophilic carbon atoms, respectively. By simple permutations of enantiomers of the two catalysts, all four stereoisomers of products containing two stereogenic centers were synthesized individually with high diastereoselectivity and enantioselectivity. A variety of azaaryl acetamides and acetates bearing pyridyl, benzothiazolyl, benzoxazolyl, pyrazinyl, quinolinyl and isoquinolinyl moieties were all found to be suitable for this transformation.

Effects of catalyst activation and ligand steric properties on the enantioselective allylation of amines and phenoxides

(Chemical Equation Presented) The yields, enantioselectivities, and regioselectivities of the reactions of amines and phenoxides with allylic carbonates in the presence of a metallacyclic iridium catalyst were compared. These data show that both preactiva