6763-47-9

Basic information

• Product Name: 1,2-O-Cyclohexylidene-myo-inositol
• Synonyms: (3aR,4S,5R,6R,7S,7aS)-Hexahydrospiro[1,3-benzodioxole-2,1'-cyclohexane]-4,5,6,7-tetrol;1,2-O-Cyclohexylidene-DL-Myo-inositol;NSC 156930
• CAS NO: 6763-47-9
• Molecular Formula: C₁₂H₂₀O₆
• Molecular Weight: 260.284
• Product Categories: All Inositols;Inositols
• Mol File: 6763-47-9.mol
• Article Data: 15

Chemical Properties

• Melting Point: 176-178°C
• Boiling Point: 466.4±45.0 °C(Predicted)
• Appearance: /
• Density: 1.46±0.1 g/cm3(Predicted)
• Storage Temp.: -20?C Freezer
• PKA: 12.87±0.70(Predicted)
• CAS DataBase Reference: 1,2-O-Cyclohexylidene-myo-inositol(CAS DataBase Reference)
• NIST Chemistry Reference: 1,2-O-Cyclohexylidene-myo-inositol(6763-47-9)
• EPA Substance Registry System: 1,2-O-Cyclohexylidene-myo-inositol(6763-47-9)

Safety Data

• Hazardous Substances Data: 6763-47-9(Hazardous Substances Data)

Usage

Description

1,2-O-Cyclohexylidene-myo-inositol, with the chemical abstracts service number 6763-47-9, is a significant compound that plays a crucial role in various organic synthesis processes. It is known for its unique structure and properties that make it a valuable component in the creation of different organic compounds.

Uses

Used in Organic Synthesis:
1,2-O-Cyclohexylidene-myo-inositol is used as a key intermediate in organic synthesis for its ability to facilitate the formation of complex organic molecules. Its unique cyclohexylidene moiety allows for versatile reactions and transformations, making it a valuable asset in the synthesis of pharmaceuticals, agrochemicals, and other specialty chemicals.
Used in Pharmaceutical Industry:
In the pharmaceutical industry, 1,2-O-Cyclohexylidene-myo-inositol is used as a building block for the development of new drugs. Its unique structure can be modified to create novel compounds with potential therapeutic applications, contributing to the advancement of medicine and healthcare.
Used in Agrochemical Industry:
1,2-O-Cyclohexylidene-myo-inositol also finds application in the agrochemical industry, where it is utilized in the synthesis of new pesticides and other crop protection agents. Its versatility in organic synthesis allows for the development of innovative and effective solutions to protect crops and enhance agricultural productivity.
Used in Specialty Chemicals:
In the specialty chemicals sector, 1,2-O-Cyclohexylidene-myo-inositol is employed as a precursor for the synthesis of various specialty chemicals. Its unique properties enable the creation of high-value products used in industries such as coatings, adhesives, and plastics, among others.

Upstream product

• 933-40-4 cycloxexanone dimethyl ketal 
• 87-89-8 D-myo-inositol 
• 1670-47-9 1,1-diethoxycyclohexane 
• 34361-60-9 1,2:4,5-dicyclohexylidene-myo-inositol 
• 1122-84-5 1-ethoxycyclohexene 
• 108-94-1 cyclohexanone 

Downstream Products

• 6691-27-6 (+/-)-cis-1,2-O-cyclohexylidene-3,4,5,6-tetrakis-O-benzyl myo-inositol 
• 26276-99-3 rac-1,4,5,6-tetra-O-benzyl-myo-inositol 
• 1254-38-2 inositol peracetate 
• 39110-61-7 3,4,5,6-tetra-O-acetyl-1,2-O-cyclohexylidene-myo-inositol 
• 34361-60-9 1,2:4,5-dicyclohexylidene-myo-inositol 
• 6763-49-1 (+/-)-1,2:5,6-dicyclohexylidene-myo-inositol 
• 6763-49-1 (±)-1,2:3,4-di-O-cyclohexylidene-myo-inositol 
• 13462-79-8 1⁽³⁾,4⁽⁶⁾,5,6⁽⁴⁾-tetra-O-acetyl-sn-myo-inositol 
• 22132-86-1 meso-2,3,4,5,6-O-pentabenzyl-scyllo-inositol 
• 5160-25-8 1,3,4,5,6-Penta-O-acetyl-2-O-methansulfonyl-myo-inosit 
• 52389-41-0 1(3),3(1),4(6),5,6(4)-penta-O-acetyl-sn-myoinositol 
• 130277-51-9 DL,(6E)-1,2,3,4,5-Penta-O-benzyl-6-(methoxymethylidene)cyclohexane-1,2,4/3,5-pentol 
• 130277-51-9 DL,(6Z)-1,2,3,4,5-Penta-O-benzyl-6-(methoxymethylidene)cyclohexane-1,2,4/3,5-pentol 
• 130277-53-1 DL-3,4,5,6-Tetra-O-benzyl-3,5/4,6-tetrahydroxycyclohex-1-ene-1-methanol 

Relevant articles and documents

Inositol tetrakisphosphate from chicken eggshell

Unlike our previous study that identified D-myo-inositol 4,5-bisphosphate (Ins(4,5)P2, 1) from ostrich eggshell, the compound myo-inositol 1,4,5,6-tetrakisphosphate (Ins(1,4,5,6)P4, 2) was isolated as an almost racemic mixture from t

Efficient regioselective protection of myo-inositol via facile protecting group migration

A cis-1,2-cyclohexanediol, 1,4,5,6-tetra-O-benzyl-myo-inositol, was selectively protected at the axial C2-hydroxyl via acid-mediated rearrangement of the corresponding 1,2-orthoacetate, or via the base-induced migration of a protecting group that had previously been easily installed with complete regioselectivity at the adjacent equatorial hydroxyl. Esters 4a-6a were synthesized in high yields (75-82%) while sulfonate 7a and silyl ether 8a were obtained in 85 and 31% yields, respectively. The migration of the esters induced by DBU results in equilibrium between regioisomers favouring the C2 protected isomer, but NaH induced migration of sulfonyl and silyl groups results in complete migration from equatorial to axial hydroxyl groups.

Syntheses of penta-O-benzyl-myo-inositols, O-β-L-arabinosyl-(1 → 2)sn-myo-inositol, O-α-D-galactosyl-(1 → 3)-sn-myo-inositol, and O-α-D-galactosyl-(1 → 6)-O-α-D-galactosyl-(1 → 3)-sn-myo-inositol

Two-step conversions of myo-inositol into (±)-2,3,4,5,6- and 1,3,4,5,6-penta-O-benzyl-myo-inositols are described. Starting from these monohydroxy derivatives of myo-inositol, O-β-L-arabinopyranosyl-(1→2)-sn-myo-inositol from Japanese green tea, Camellia sinensis, and O-α-D-galactopyranosyl-(1→3)-sn-myo-inositol (galactinol) as well as its homolog, O-α-D-galactopyranosyl-(1→6(II))-galactinol, were synthesized by way of the in situ activating glycosylation procedure.