67698-66-2

Basic information

• Product Name: Benzaldehyde, 2-(2-methylphenoxy)-
• CAS NO: 67698-66-2
• Molecular Formula: C14H12O2
• Molecular Weight: 212.248
• Mol File: 67698-66-2.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: Benzaldehyde, 2-(2-methylphenoxy)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzaldehyde, 2-(2-methylphenoxy)-(67698-66-2)
• EPA Substance Registry System: Benzaldehyde, 2-(2-methylphenoxy)-(67698-66-2)

Safety Data

• Hazardous Substances Data: 67698-66-2(Hazardous Substances Data)

Upstream product

• 95-48-7 ortho-cresol 
• 446-52-6 2-Fluorobenzaldehyde 
• 552-89-6 2-nitro-benzaldehyde 
• 16419-60-6 2-Methylphenylboronic acid 
• 6630-33-7 ortho-bromobenzaldehyde 
• 89-98-5 2-chloro-benzaldehyde 
• 26260-02-6 2-iodobenzaldehyde 

Downstream Products

• 1400883-61-5 C₂₀H₁₈O₄S 
• 26321-31-3 2-(p-tolyloxy)phenol 
• 7320-53-8 4-methyl-dibenzofuran 
• 617-01-6 o-tolyl 2-hydroxybenzoate 
• 5396-28-1 4-methylxanthen-9-one 

Relevant articles and documents

An organocatalytic method for the synthesis of some novel xanthene derivatives by the intramolecular Friedel-Crafts reaction

An efficient organocatalytic method for the synthesis of new substituted 9-arylxanthenes (2a-2u) starting from diarylcarbinol compounds with an arenoxy group (1a-1u) has been developed using the intramolecular Friedel-Crafts reaction. The substrates were

Ligand-free copper-catalyzed O-arylation of nitroarenes with phenols

The first example of ligand-free copper-catalyzed O-arylation of nitroarenes with phenols was developed, achieving unsymmetrical diaryl ethers in moderate to excellent yields. This arylation proceeded smoothly without promotion of the ligands, and displayed great functional group compatibility. Thus, the method represents a new, facile, and cost-effective approach to access unsymmetrical diaryl ethers.

The coupling of arylboronic acids with nitroarenes catalyzed by rhodium

The coupling of arylboronic acids with electron-deficient nitroarenes was realized for the first time by using a rhodium(I) catalyst under an air atmosphere, achieving unsymmetrical diaryl ethers with yields ranging from poor to good. From a deuterium labeling experiment, the oxygen atom is derived from ambient water. The efficiency of this reaction was demonstrated by its compatibility with fluoro, bromo, chloro, and trifluoromethyl groups.