678-45-5Relevant articles and documents
Reaction of Perfluoroalkanesulfinates with Allyl and Propargyl Halides. A Convenient Synthesis of 3-(Perfluoroalkyl)prop-1-enes and 3-(Perfluoroalkyl)allenes
Hu, Chang-Ming,Qing, Feng-Ling,Huang, Wei-Yuan
, p. 2801 - 2804 (2007/10/02)
The reaction of perfluoroalkanesulfinates, RfCF2SO2Na, with allyl and propargyl halides, in the presence of (NH4)2S2O8, gave 3-(perfluoroalkyl)prop-1-enes (RfCH2CH=CH2) and 3-(perfluoroalkyl)allenes (RfCH=C=CH2), respectively, in good yield.Evidence is presented for a radical addition-elimination mechanism for the reaction.The reaction represents a synthetically viable and convenient route to such compounds.
REACTIONS OF PERHALOCARBONS. PART IX. CONVERSION OF PER(POLY)FLUOROALKYL HALIDES INTO THE CORRESPONDING CARBOCYCLIC ACIDS WITH A REDOX SYSTEM
Hu, Chang-Ming,Qing, Feng-Ling,Zhang, Hong-Gen
, p. 275 - 280 (2007/10/02)
The conversion of per(poly)fluoroalkylhalides into the corresponding carbocyclic acids with a redox system-(NH4)2S2O8/HCO2Na is described.The reaction provides a convenient method for the synthesis of various per(poly)fluorocarboxylic acids under mild conditions.
A CONVENIENT METHOD FOR THE PREPARATION OF PERFLUORODICARBOXYLIC ACIDS
Nguyen, T.,Rubinstein, M.,Wakselman, C.
, p. 81 - 86 (2007/10/02)
-