67858-83-7

Basic information

• Product Name: ethyl (2E,6E)-8-benzyloxy-2,6-dimethyl-2,6-octadienoate
• Synonyms: ethyl (2E,6E)-8-benzyloxy-2,6-dimethyl-2,6-octadienoate
• CAS NO: 67858-83-7
• Molecular Weight: 302.414
• Mol File: 67858-83-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: ethyl (2E,6E)-8-benzyloxy-2,6-dimethyl-2,6-octadienoate(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl (2E,6E)-8-benzyloxy-2,6-dimethyl-2,6-octadienoate(67858-83-7)
• EPA Substance Registry System: ethyl (2E,6E)-8-benzyloxy-2,6-dimethyl-2,6-octadienoate(67858-83-7)

Safety Data

• Hazardous Substances Data: 67858-83-7(Hazardous Substances Data)

Upstream product

• 52188-73-5 geranyl benzyl ether 
• 106-24-1 Geraniol 
• 32989-52-9 (E)-4-methyl-6-(phenylmethoxy)-4-hexenal 
• 21382-82-1 (carbethoxyethylidene)triphenylphosphorane 

Downstream Products

• 81757-30-4 (2E,6E)-<1,1-2H2>-8-Benzyloxy-2,6-dimethyl-2,6-octadienol 
• 360042-90-6 (2E,6E)-(1,1-2H₂)-8-benzyloxy-2,6-dimethyl-2,6-octadien-1-yl diethyl phosphate 
• 81757-32-6 Benzyl((2E,6E)-<8,8,8-2H3>-8-brom-3,7-dimethyl-2,6-octadienyl)aether 
• 52188-74-6 (E,E)-8-acetoxy-1-benzyloxy-3,7-dimethylocta-2,6-diene 

Relevant articles and documents

Stereochemical disposition of the geminal dimethyl groups in the enzymatic cyclization of geranyl diphosphate to (+)-bornyl diphosphate by recombinant (+)-bornyl diphosphate synthase from Salvia officinalis

Regiospecifically deuterated geranyl diphosphate, in concert with NMR spectrometry, was employed to demonstrate that the trans-methyl group (C8) of geranyl diphosphate becomes the C9 carbon of (+)-bornyl diphosphate (geminal methyl syn to the diphosphate moiety) and that the cis-methyl group (C9) becomes the C8 (geminal methyl anti to the diphosphate). The syntheses of the relevant substrates and products, with accompanying spectrometric data are provided.