680602-24-8

Basic information

• Product Name: [P(C₆H₄CH₂NMe₂-2)3]2AgO₄C₁₄H₆
• CAS NO: 680602-24-8
• Molecular Weight: 1321.09
• Mol File: 680602-24-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: [P(C₆H₄CH₂NMe₂-2)3]2AgO₄C₁₄H₆(CAS DataBase Reference)
• NIST Chemistry Reference: [P(C₆H₄CH₂NMe₂-2)3]2AgO₄C₁₄H₆(680602-24-8)
• EPA Substance Registry System: [P(C₆H₄CH₂NMe₂-2)3]2AgO₄C₁₄H₆(680602-24-8)

Safety Data

• Hazardous Substances Data: 680602-24-8(Hazardous Substances Data)

Upstream product

• 620591-70-0 C₁₄H₆(O)2(OAg)2 
• 23936-58-5 Tris<2-(dimethylaminomethyl)phenyl>phosphan 

Relevant articles and documents

Mono- and bimetallic silver(I) complexes with bridging and terminal-bound organic chelating ligands

The synthesis of the mononuclear and homobimetallic silver(I) complexes [P(C6H4CH2NMe2-2) 3]AgL2 [L2=acetylacetonate, acac (5a); tropolonate, trop (5b); 3-hydroxy-2-methyl-γ-pyranoate, pyro (5c)], [P(C6H4CH2NMe2-2) 3]AgOC(O)Me (8) and [P(C6H4CH 2NMe2-2)3]Ag-L4-Ag[P(C 6H4CH2NMe2-2)3] [L 4=2,5-dihydroxy-p-benzochinoate, benz (6a); 1,4-dihydroxy- anthrachinoate, anthra (6b)] can be achieved by the reaction of the silver(I) salts [AgL2] [L2=acac (3a), trop (3b), pyro (3c)], [Ag2L4] [L4=benz (3d), anthra (3e)] or [AgCO2Me] (7) with P(C6H4CH2NMe 2-2)3 (4) in a 1:1 or 1:2 molar ratio. The respective silver(I) salts 3a-3e are accessible by treatment of [AgNO3] (1) with HL2 or H2L4 (2a-2d), respectively. In 5a-5c, 6a and 6b the silver atom possesses a pseudotetrahedral environment caused by the chelate-bound ligands acac, trop, pyro, benz or anthra and the bidentate coordinated phosphane 4. In homobimetallic 6a and 6b the appropriate transition metals are spanned by the benz or anthra units, respectively. While in 5a-5c, 6a and 6b the silver metal possesses the coordination number 4, in 8 a T-shaped arrangement is set-up with a linear P-Ag-O unit. The chemical and physical behaviour of complexes 5a-5c, 6a, 6b and 8 is reported. Spectroscopic studies reveal that on the NMR time-scale the phosphane group with its Me 2NCH2 built-in arms is dynamic.