68089-73-6Relevant articles and documents
Synthesis of Tribenzotropone by Ring Expansion of Phenanthrene-9,10-dione
Choi, Jeongae,Jung, Hyunuk,Yeo, Jeong-Eun,Koo, Sangho
, p. 2957 - 2960 (2015)
Tribenzotropone was efficiently synthesized by a ring-expansion method from readily available phenanthrene-9,10-dione via a ring-opened diketone as a key intermediate; the diketone was prepared by nucleophilic addition of allyl and vinyl groups, followed by an oxidative ring-opening reaction with lead(IV) acetate. Ring closure by an intramolecular Diels-Alder reaction and subsequent dehydrogenation produced tribenzotropone in 38% overall yield. Ring closure by a Morita-Baylis-Hillman reaction, on the other hand, produced a dibenzo-fused nonanedione in 22% overall yield.
COMPOUND AND ORGANIC ELECTRONIC DEVICE COMPRISING THE SAME
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Paragraph 0054; 0060-0061, (2019/12/25)
Provided are a novel compound and an organic electronic device using the same. The novel compound is represented by the following Formula (I): G1 and G2 in Formula (I) are each independently selected from the group consisting of: and
NOBEL COMPOUND AND ORGANIC ELECTRONIC DEVICE INCLUDING THE SAME
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Paragraph 0065-0067; 0072-0074, (2019/04/03)
PROBLEM TO BE SOLVED: To provide a novel compound which improves luminous efficiency and a device life of an organic light-emitting device. SOLUTION: A novel compound is represented by a formula (I) [Ar1-Ar4 are each independently H, D, an alkyl group, an aryl group, a heterocyclic group or the like; L and Q are each independently an arylene group; G is D, an alkyl group, an aryl group, a heterocyclic group or the like; n1 and n2 are each independently 0 or 1; and m1, m2 and q are each independently an integer of 0-2]. SELECTED DRAWING: None COPYRIGHT: (C)2019,JPOandINPIT