681851-29-6

Basic information

• Product Name: Morpholine, 3-(bromomethyl)-4-(phenylmethyl)-, (3S)-
• CAS NO: 681851-29-6
• Molecular Formula: C12H16BrNO
• Molecular Weight: 270.169
• Mol File: 681851-29-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Morpholine, 3-(bromomethyl)-4-(phenylmethyl)-, (3S)-(CAS DataBase Reference)
• NIST Chemistry Reference: Morpholine, 3-(bromomethyl)-4-(phenylmethyl)-, (3S)-(681851-29-6)
• EPA Substance Registry System: Morpholine, 3-(bromomethyl)-4-(phenylmethyl)-, (3S)-(681851-29-6)

Safety Data

• Hazardous Substances Data: 681851-29-6(Hazardous Substances Data)

Upstream product

• 101376-26-5 (3R)-4-benzyl-3-(hydroxymethyl)-morpholine 
• 106973-40-4 ethyl (S)-5-oxo-4-(phenylmethyl)morpholine-3-carboxylate 
• 106973-37-9 (3S)-5-oxo-4-(phenylmethyl)-3-morpholinecarboxylic acid 
• 106910-76-3 (S)-2-(benzylamino)-3-hydroxypropanoic acid 

Downstream Products

• 681851-33-2 2,2,2-trichloro (S)-3-{[(phenylmethyl)sulfanyl]methyl}morpholine-4-carboxylate 
• 681851-35-4 (S)-3-{[(phenylmethyl)sulfanyl]methyl}morpholine 
• 681851-31-0 (S)-4-(phenylmethyl)-3-{[(phenylmethyl)sulfanyl]methyl}morpholine 

Relevant articles and documents

Properties and Reactions of Substituted 1,2-Thiazetidine 1,1-Dioxides: Chiral Mono- and Bicyclic 1,2-Thiazetidine 1,1-Dioxides from α-Amino Acids

New chiral mono- and bicyclic β-sultams, valuable building blocks for drug synthesis, have been prepared from L-Ala, L-Val, L-Leu, L-Ile, L-Phe, L-Cys, L-Ser, L-Thr, and D-penicillamine by transformation of the COOH group into a methylsulfonyl chloride function, followed by cyclization under basic conditions. Selected properties, derivatives, and reactions of the β-sultams are described.