683-81-8Relevant articles and documents
Fluorinating agent and synthesis method thereof
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Paragraph 0054-0056, (2020/09/16)
The invention discloses a fluorinating agent, and also discloses a preparation method of the fluorinating agent, wherein an amide corresponding to the structural formula of the product reacts with a halogenating agent to obtain corresponding alpha, alpha-dihaloamine, and the alpha, alpha-dihaloamine reacts with a fluoride to obtain the corresponding fluorinating agent. The fluorinating agent has the advantages of being stable in storage and capable of fluorinating hydroxyl with high yield, the preparation method is simple, the adopted raw materials are easy to obtain, the synthesis yield is high, and the fluorinating efficiency of the obtained product is high.
Phosphorus(V) complexes with acyclic monoaminocarbene ligands via oxidative addition
B?ttcher, Tobias,Bassil, Bassem S.,Zhechkov, Lyuben,R?schenthaler, Gerd-Volker
supporting information, p. 5651 - 5653 (2013/07/04)
(Difluoroorganyl)dimethylamines, RCF2NMe2 (R = H, Ph, tBu), can be used as carbene precursors for phosphorus trifluoride in an oxidative addition reaction. By this method, complexes of sterically nondemanding asymmetric and acyclic c