68318-08-1

Basic information

• Product Name: 2'-Methyl-2'-(phenylsulfinyl)spiro
• Synonyms: 2'-Methyl-2'-(phenylsulfinyl)spiro
• CAS NO: 68318-08-1
• Molecular Weight: 264.389
• Mol File: 68318-08-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 2'-Methyl-2'-(phenylsulfinyl)spiro(CAS DataBase Reference)
• NIST Chemistry Reference: 2'-Methyl-2'-(phenylsulfinyl)spiro(68318-08-1)
• EPA Substance Registry System: 2'-Methyl-2'-(phenylsulfinyl)spiro(68318-08-1)

Safety Data

• Hazardous Substances Data: 68318-08-1(Hazardous Substances Data)

Upstream product

• 134671-01-5 1-(1-Benzenesulfinyl-1-chloro-ethyl)-cycloheptanol 
• 26910-40-7 1-chloroethyl phenyl sulfoxide 
• 502-42-1 cycloheptanone 

Downstream Products

• 14377-11-8 1-acetyl-1-cycloheptene 

Relevant articles and documents

A Novel Synthesis of Methylenecyclopropane Spiro-Linked with Cycloalkanes via a Cyclization of Allylic Epoxides and Its Application to a Synthesis of Fused 3-Methylfurans

Ring closure of allylic epoxides derived from 1-chloroalkyl phenyl sulfoxides and cyclic ketones with lithium diisopropylamide (LDA) in 3-Exo-Tet mode gave spiro-linked methylenecyclopropanes having a hydroxyl group in good yields.Oxidation of these compounds gave ketones, which were then treated with p-toluenesulfonic acid in 1,4-dioxane or DMSO at 100 deg C to give fused 3-methylfurans in good overall yields.This procedure was applied to a synthesis of menthofuran from 4-methylcyclohexanone.