68423-18-7

Basic information

• Product Name: 1-(1-phenylvinyl)cyclopropanol
• Synonyms: 1-(1-phenylvinyl)cyclopropanol
• CAS NO: 68423-18-7
• Molecular Weight: 160.216
• Mol File: 68423-18-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1-(1-phenylvinyl)cyclopropanol(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(1-phenylvinyl)cyclopropanol(68423-18-7)
• EPA Substance Registry System: 1-(1-phenylvinyl)cyclopropanol(68423-18-7)

Safety Data

• Hazardous Substances Data: 68423-18-7(Hazardous Substances Data)

Upstream product

• 98-81-7 1-bromovinylbenzene 
• 29526-99-6 1-methylcyclopropanol 
• 98-86-2 acetophenone 
• 5009-27-8 cyclopropanone 
• 68423-23-4 1-Brom-1-phenylspiropentan 

Downstream Products

• 1599438-41-1 2-benzyl-2-phenylcyclobutanone 

Relevant articles and documents

Electrophilic Trifluoromethylthiolation/Semipinacol Rearrangement: Preparation of β-SCF3 Carbonyl Compounds with α-Quaternary Carbon Center

A new and modular electrophilic trifluoromethylthiolation/semipinacol rearrangement of allylic silyl ethers has been developed under mild conditions. This approach allows the formation of a number of β-SCF3 carbonyl compounds with a cyclic and all-carbon quaternary center framework in moderate to good yields. It should be noted that this achievement is a metal-free process and just requires the use of simple acetyl chloride as an acidic promoter. Additionally, an interesting H-migration in competition with aryl-migration process was revealed.