684284-10-4

Basic information

• Product Name: Bicyclo[2.2.1]heptane-2-methanol, 7,7-dimethyl-, (1R,2R,4S)- (9CI)
• Synonyms: Bicyclo[2.2.1]heptane-2-methanol, 7,7-dimethyl-, (1R,2R,4S)- (9CI)
• CAS NO: 684284-10-4
• Molecular Formula: C10H18O
• Molecular Weight: 154.24932
• Product Categories: CYCLOPENTANE
• Mol File: 684284-10-4.mol
• Article Data: 1

Chemical Properties

• Boiling Point: 219.5±8.0 °C(Predicted)
• Appearance: /
• Density: 0.950±0.06 g/cm3(Predicted)
• PKA: 15.05±0.10(Predicted)
• CAS DataBase Reference: Bicyclo[2.2.1]heptane-2-methanol, 7,7-dimethyl-, (1R,2R,4S)- (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Bicyclo[2.2.1]heptane-2-methanol, 7,7-dimethyl-, (1R,2R,4S)- (9CI)(684284-10-4)
• EPA Substance Registry System: Bicyclo[2.2.1]heptane-2-methanol, 7,7-dimethyl-, (1R,2R,4S)- (9CI)(684284-10-4)

Safety Data

• Hazardous Substances Data: 684284-10-4(Hazardous Substances Data)

Upstream product

• 75-54-7 Dichloromethylsilane 
• 116724-26-6 α-fenchene 
• 1156-31-6 toluene-4-sulfonic acid-((1S)-1,3,3-trimethyl-[2endo]norbornyl ester) 
• 7378-37-2 α-fenchene 

Relevant articles and documents

Chiral organochlorosilanes derived from terpenes: Diastereoselective hydrosilylation of methylene bicyclo[2.2.1]heptanes with HSiMenCln-2 (n = 0-2)

The H2PtCl6 catalysed hydrosilylation of the terpenes (+)-α-fenchene (XI), (-)-2-methylene bornane (XII), (+)-camphene (XIII) and (-)-3-methylene fenchane (XIV) using HSiMe2Cl or HSiMeCl2 proceeds with high regioselectively and in some cases, with high diastereoselectivity. KF-assisted oxidation of the hydrosilylation products gives predominately endo-terpene alcohols. The alcohols have inverted endo/exo ratios to those formed by oxidative hydroboration. Reaction of XIV with HSiMe2Cl or HSiMeCl2 is accompanied by a clean rearrangement of the isocamphane skeleton into (+)-2-methylene bornane (XII) prior to hydrosilylation.