68487-06-9

Basic information

• Product Name: 1-(1-hydroxycyclohexyl)-1-butanone
• Synonyms: 1-(1-hydroxycyclohexyl)-1-butanone
• CAS NO: 68487-06-9
• Molecular Weight: 170.252
• Mol File: 68487-06-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1-(1-hydroxycyclohexyl)-1-butanone(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(1-hydroxycyclohexyl)-1-butanone(68487-06-9)
• EPA Substance Registry System: 1-(1-hydroxycyclohexyl)-1-butanone(68487-06-9)

Safety Data

• Hazardous Substances Data: 68487-06-9(Hazardous Substances Data)

Upstream product

• 2861-18-9 acetic acid-(1-but-3-en-1-ynyl-cyclohexyl ester) 
• 72252-20-1 1-(1'-acetoxycyclohexyl)-2-buten-1-one 
• 107153-19-5 1-(1-acetoxy-cyclohexyl)-but-3-en-1-one 
• 2696-22-2 1-vinylethynyl-1-cyclohexanol 
• 108-94-1 cyclohexanone 
• 134857-90-2 1-(1-chloro-1,2-epoxybutyl)-1-cyclohexanol 
• 109-74-0 propyl cyanide 
• 78-82-0 Isobutyronitrile 
• 105520-28-3 1-(1-acetoxy-cyclohexyl)-butan-1-one 

Relevant articles and documents

Electroorganic Chemistry. 140. Electroreductively Intra- and Intermolecular Couplings of Ketones with Nitriles

Electroreduction of γ- and δ-cyano ketones in i-PrOH with Sn cathode gave α-hydroxy ketones and their dehydroxylated ketones as the intramolecularly coupled products.Guaiazulene, (-)-valeranone, polyquinanes, dihydrojasmone, methyl dihydrojasmonate, and rosaprostol have been synthesized by utilizing this electroreductive intramolecular coupling of γ- and δ-cyano ketones in one of the key steps.Similarly, electroreduction of a mixture of ketone and nitrile gave the corresponding intermolecularly coupled product.The product obtained by the electroreductive intermolecular coupling of (+)-dihydrocarvone with acetonitrile has been found to be the precursor of an effective chiral ligand for the enantioselective addition of diethylzinc to aldehydes.