68774-47-0

Basic information

• Product Name: (2R,3R,4R,5R)-3,4-dihydroxy-2,5-di(trityloxymethyl)tetrahydrofuran
• Synonyms: (2R,3R,4R,5R)-3,4-dihydroxy-2,5-di(trityloxymethyl)tetrahydrofuran
• CAS NO: 68774-47-0
• Molecular Weight: 648.799
• Mol File: 68774-47-0.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: (2R,3R,4R,5R)-3,4-dihydroxy-2,5-di(trityloxymethyl)tetrahydrofuran(CAS DataBase Reference)
• NIST Chemistry Reference: (2R,3R,4R,5R)-3,4-dihydroxy-2,5-di(trityloxymethyl)tetrahydrofuran(68774-47-0)
• EPA Substance Registry System: (2R,3R,4R,5R)-3,4-dihydroxy-2,5-di(trityloxymethyl)tetrahydrofuran(68774-47-0)

Safety Data

• Hazardous Substances Data: 68774-47-0(Hazardous Substances Data)

Upstream product

• 76-83-5 trityl chloride 
• 41107-82-8 2,5-anhydro-D-mannitol 
• 23261-20-3 1,2:5,6-dianhydrogalactitol 
• 495-75-0 2,5-anhydro-D-mannose 
• 1078691-95-8 (+)-D-glucosamine hydrochloride 

Downstream Products

• 292069-07-9 (2S,5S)-2,5-di(trityloxymethyl)-2,5-dihydrofuran 
• 454474-68-1 (2R,3R,4R,5R,6S,9S,10S,13R,14S)-3,4-bis(tert-butyldimethylsilyloxy)-2,5:10,14-dioxido-6,9,13-tris(methoxymethoxy)-1-trityloxytetracosane 
• 454474-67-0 (2R,3R,4R,5R,6S,10S,13R,14S)-3,4-bis(tert-butyldimethylsilyloxy)-2,5:10,14-dioxido-6,13-bis(methoxymethoxy)-1-trityloxytetracosan-9-one 
• 454475-02-6 (S)-4-[(2R,3R,4R,5R)-3,4-Bis-(tert-butyl-dimethyl-silanyloxy)-5-trityloxymethyl-tetrahydro-furan-2-yl]-1-((2S,5R,6S)-6-decyl-5-methoxymethoxy-tetrahydro-pyran-2-yl)-4-methoxymethoxy-butan-1-ol 
• 220772-76-9 (2R,3R,4R,5R,6S,9RS,10S,13R,14S)-3,4-bis(tert-butyldimethylsilyloxy)-2,5:10,14-dioxido-6,13-bis(methoxymethoxy)-1-trityloxytetracos-7-yn-9-ol 
• 220772-77-0 (2R,3R,4R,5R,6S,9S,10S,13R,14S)-3,4-bis(tert-butyldimethylsilyloxy)-2,5:10,14-dioxido-6,13-bis(methoxymethoxy)-1-trityloxytetracosan-9-ol 
• 220772-80-5 (2R,3R,4R,5R,6S,9S,10S,13R,14S)-2,5:10,14-dioxido-3,4-bis(methanesulfonyloxy)-6,9,13-tris(methoxymethoxy)-1-trityloxytetracosane 
• 220772-79-2 (2R,3S,4S,5S,6S,9S,10S,13R,14S)-2,5:10,14-dioxido-6,9,13-tris(methoxymethoxy)-1-trityloxytetracosane-3,4-diol 
• 454474-70-5 (2S,5S,6S,9S,10S,13R,14S)-2,5:10,14-dioxido-6,9,13-tris(methoxymethoxy)-1-trityloxytetracosane 
• 220772-81-6 (2S,5S,6S,9S,10S,13R,14S)-2,5:10,14-dioxido-6,9,13-tris(methoxymethoxy)-1-trityloxytetracos-3-ene 
• 220772-75-8 (2R,3R,4R,5R)-3,4-di-tert-butyldimethylsilyloxy-2-[(1S)-(1-methoxymethyloxy)ethynyl]-5-(1-trityloxymethyl)tetrahydrofuran 
• 220772-74-7 (2R,3R,4R,5R)-3,4-di-tert-butyldimethylsilyloxy-2-[(1S)-(1-hydroxy)ethynyl]-5-(1-trityloxymethyl)tetrahydrofuran 
• 220772-71-4 (2R,3R,4R,5R)-3,4-di-tert-butyldimethylsilyloxy-5-(hydroxymethyl)-2-(1-trityloxymethyl)tetrahydrofuran 
• 220772-72-5 (2S,3R,4R,5R)-3,4-di-tert-butyldimethylsilyloxy-2-formyl-5-(1-trityloxymethyl)tetrahydrofuran 

Relevant articles and documents

Synthesis of poly-O-sulfated glycosides of 2,5-anhydro-D-mannitol

2,5-Anhydro-3-O-β-d-glucopyranosyl-; -3-O-α-l-idopyranosyl-; -3-O-α-d-arabinopyranosyl-; -3-O-α-l-arabinopyranosyl-; -3-O-β-d-maltopyranosyl-; -3-O-β-d-gentiobiopyranosyl-; -1,6-di-O-β-d-glucopyranosyl-; -1,6-di-O-α-l-idopyranosyl-; -1-O-β-d-maltopyranosy

Chiral diphosphorus compounds and transition metal complexes thereof

Tetrahydrofuran bisphosphines of formula (I), are new. Tetrahydrofuran bisphosphines of formula (I): X1, X2 = bonds or O; R1, R2 = H, 1-20C alkyl, 1-20C fluoroalkyl, 2-20C alkenyl, 4-24C aryl, 5-25C aralkyl, 6-26C aralkenyl, NR7R8, OR8, AOR8, ANR7R8 or OC

Synthesis of 3-deoxy-3-nucleobase-2,5-anhydro-D-mannitol: A novel class of hydroxymethyl-branched isonucleosides

A concise synthesis of 3-deoxy-3-nucleobase-2,5-anhydro-D-mannitol 6(a- d) has been achieved, using the deamination of 2-amino-2-deoxy-D-glucose to construct in one step the sugar skeleton with the desired sense of chirality at each asymmetric center. The selective dibenzoylation of 2,5-anhydro-D- mannitol 9 was investigated, and the key epoxide intermediate 13 was obtained in good yield via an intramolecular Mitsunobu reaction. The process of opening of epoxide 13 by nucleobases appeared to be regioselective. (C) 2000 Elsevier Science Ltd.