6879-76-1

Basic information

• Product Name: 2-O-Methyllycorine
• CAS NO: 6879-76-1
• Molecular Weight: 301.342
• Mol File: 6879-76-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-O-Methyllycorine(CAS DataBase Reference)
• NIST Chemistry Reference: 2-O-Methyllycorine(6879-76-1)
• EPA Substance Registry System: 2-O-Methyllycorine(6879-76-1)

Safety Data

• Hazardous Substances Data: 6879-76-1(Hazardous Substances Data)

Upstream product

• 69787-57-1 (1S,2S,3a¹S,12bS)-2-chloro-2,3a¹,4,5,7,12b-hexahydro-1H-[1,3]dioxolo[4,5-j]pyrrolo[3,2,1-de]-phenanthridin-1-yl acetate 

Relevant articles and documents

Stereoselective Transformation of the Alkaloid Lycorine to O-Demethylungiminorine and Ungiminorine

Diacetyllycorine, an Amaryllidaceae alkaloid, was transformed stereoselectively to the more heavily oxygenated congener, O-demethylungiminorine, by a route similar to that suggested for the biosynthesis of narcissidine.Similarly, acetylhippamine was converted to ungiminorine.A method of high yield conversion of lycorine to hippamine is also described. - The above transformations constitute a formal total synthesis of ungiminorine.Keywords--- Amaryllidaceae alkaloid; lycorine; hippamine; ungiminorine; O-demethylungiminorine; lycorine-chlorohydrin; permanganate oxidation; phosphoryl chloride; stereoselective hydroxylation; distorted boat conformation