68936-07-2

Basic information

• Product Name: 14-chloro-5,10-dioxatetradecan-1-ol
• Synonyms: 14-chloro-5,10-dioxatetradecan-1-ol
• CAS NO: 68936-07-2
• Molecular Weight: 252.782
• Mol File: 68936-07-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 14-chloro-5,10-dioxatetradecan-1-ol(CAS DataBase Reference)
• NIST Chemistry Reference: 14-chloro-5,10-dioxatetradecan-1-ol(68936-07-2)
• EPA Substance Registry System: 14-chloro-5,10-dioxatetradecan-1-ol(68936-07-2)

Safety Data

• Hazardous Substances Data: 68936-07-2(Hazardous Substances Data)

Upstream product

• 109-99-9 tetrahydrofuran 

Relevant articles and documents

Metal-assisted Reactions. Part 17. Ring-opening and Dimerization of Cyclic Ethers by Titanium Halides

Reaction of TiCl4 or TiBr4 with a variety of cyclic ethers gives, predominantly, products resulting from simple ring-opening or from ring-opening with simultaneous condensation to dimeric species.The variations in yields of these two kinds of products might be correlated qualitatively with an initial formation of the complex TiX4*2E (X = Cl or Br; E = cyclic ether) in which the ethers were held in a cis or trans relationship.Although such a correlation might suggest that TiCl4 but not TiBr4 exerts a template effect on the condensation, stereochemical considerations of the reaction products indicate otherwise.TiCl3 and VCl3 do not give similar results and TiF4 gives no reaction.