69161-61-1

Basic information

• Product Name: 2-(prop-2-en-1-yloxy)oxane
• CAS NO: 69161-61-1
• Molecular Weight: 142.198
• Mol File: 69161-61-1.mol
• Article Data: 64

Chemical Properties

• CAS DataBase Reference: 2-(prop-2-en-1-yloxy)oxane(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(prop-2-en-1-yloxy)oxane(69161-61-1)
• EPA Substance Registry System: 2-(prop-2-en-1-yloxy)oxane(69161-61-1)

Safety Data

• Hazardous Substances Data: 69161-61-1(Hazardous Substances Data)

Upstream product

• 110-87-2 3,4-dihydro-2H-pyran 
• 6089-04-9 3-(tetrahydropyran-2'-yloxy)propyne 
• 73746-50-6 2-allyloxy-3-bromotetrahydropyran 
• 33821-94-2 3-(tetrahydro-2H-pyran-2-yloxy)propyl bromide 
• 598-25-4 Dimethylallene 
• 917-54-4 methyllithium 
• 107-18-6 allyl alcohol 

Downstream Products

• 694-54-2 tetrahydro-2H-2-pyranol 
• 13686-96-9 nonane-1,5-diol 
• 7310-51-2 oct-7-ene-1,5-diol 
• 107-02-8 acrolein 
• 583-04-0 vinyl benzoate 
• 156049-37-5 C₁₅H₁₇NO₂ 
• 112471-51-9 2-(3-phenylpropoxy)tetrahydro-2H-pyran 
• 1011-61-6 1-phenylpentane-1,5-diol 
• 1566533-35-4 dimethyl(5-phenylpent-1-yn-1-yl)(3-((tetrahydro-2H-pyran-2-yl)oxy)propyl)silane 
• 1227297-04-2 (R)-N-((1R)-1-(diphenyl(3-((tetrahydro-2H-pyran-2-yl)oxy)propyl)silyl)-3-methylbutyl)-2-methylpropane-2-sulfinamide 
• 71-23-8 propan-1-ol 
• 6581-64-2 2-propoxy-tetrahydro-pyran 
• 1927-63-5 2-hexyloxy-tetrahydro-pyran 
• 709-83-1 2-(cyclohexyloxy)tetrahydro-2H-pyran 

Relevant articles and documents

Mild and efficient tetrahydropyranylation of alcohols-catalysis by lithium perchlorate in diethyl ether

Treatment of 3,4-dihydro-2H-pyran 1 with various alcohols 2 - 10 furnished the tetrahydropyranyl ethers 11 - 19 in the presence of 5M lithium perchlorate in diethyl ether (5M LPDE), which is essentially a neutral medium.

Selective Semi-Hydrogenation of Terminal Alkynes Promoted by Bimetallic Cu-Pd Nanoparticles

The selective semi-hydrogenation of terminal alkynes was efficiently performed, under mild reaction conditions (H 2 balloon, 110 °C), promoted by a bimetallic nanocatalyst composed of copper and palladium nanoparticles (5:1 weight ratio) supported on mesostructured silica (MCM-48). The Cu-PdNPS@MCM-48 catalyst, which demonstrated to be highly chemoselective towards the alkyne functionality, is readily prepared from commercial materials and can be recovered and reused after thermal treatment followed by reduction under H 2 atmosphere.

Iron(II) catalyzed reductive radical cyclization reactions of bromoacetals in the presence of NaBH4: optimization studies and mechanistic insights

5-Exo-trig radical reductive cyclization reactions of bromoacetals are catalyzed by iron in the presence of the reducing agent NaBH4. Both iron(II) and iron(III) were found to effectively mediate these reactions. As shown by cyclic voltammetry, iron(III) can be reduced to an iron(II) precatalyst before passing through an identical reaction mechanism in which monoelectronic activation of the substrate would occur by an anionic hydridoiron(I) complex. Further studies have established that both the substrate (iodo- vs bromo-derivative) and the precatalytic mixture are decisive in determining the reaction outcome.