691860-37-4

Basic information

• Product Name: 2-methoxy-4-vinylphenyl 2-bromoacetate
• Synonyms: 2-methoxy-4-vinylphenyl 2-bromoacetate
• CAS NO: 691860-37-4
• Molecular Weight: 285.137
• Mol File: 691860-37-4.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 2-methoxy-4-vinylphenyl 2-bromoacetate(CAS DataBase Reference)
• NIST Chemistry Reference: 2-methoxy-4-vinylphenyl 2-bromoacetate(691860-37-4)
• EPA Substance Registry System: 2-methoxy-4-vinylphenyl 2-bromoacetate(691860-37-4)

Safety Data

• Hazardous Substances Data: 691860-37-4(Hazardous Substances Data)

Upstream product

• 97-53-0 4-allylguaiacol 
• 598-21-0 2-Bromoacetyl bromide 
• 22118-09-8 2-bromoacetyl chloride 

Downstream Products

• 532-08-1 4-allyl-2-methoxyphenyl cinnamate 
• 691860-39-6 (carbo-4-allyl-2-methoxyphenyloxymethylene)triphenylphosphorane 
• 1316665-06-1 nicotinic acid 4-allyl-2-methoxy-phenoxycarbonylmethyl ester hydrochloride 

Relevant articles and documents

Post-synthetic functionalization of tryptophan protected peptide sequences through indole (C-2) photocatalytic alkylation

We report a selective, mild, and efficient C-H functionalization of tryptophan and tryptophan-containing peptides with activated α-bromo-carbonyl compounds under visible-light irradiation. The protocol efficiency is outlined by the wide substrate scope and excellent tolerance of sensitive functional groups present in the amino acid side chains. The method can be successfully extended to access pharmaco-peptide conjugate scaffolds.

Useful synthesis of aryl cinnamates: synthesis of difengpin

A convenient high yield and general method is described for the synthesis of difengpin (8a) and aryl cinnamates (8b-h and 9a,b) from benzaldehydes (7a-h)