692-52-4Relevant articles and documents
Reaction of Hexachlorodisilane with Trichloroethynylsilane and 2-Propynyl Chloride in the Gas Phase
Chernyshev,Komalenkova,Kapitova,Bykovchenko,Khromykh,Bochkarev
, p. 1043 - 1046 (2007/10/03)
Reaction of acetylenic compounds (trichloroethynylsilane and 2-propynyl chloride) with hexachlorodisilane in the gas phase at 450-520°C was studied. Main products of the reaction were identified, and a mechanism of their formation was proposed. It was shown that of the two reaction centers of 2-propynyl chloride (C=≡C and C-Cl) only the C-Cl bond is involved in reaction with dichlorosilylenes generated from hexachlorodisilane.
Gas-phase reactions of hexachlorodisilane with chloroform, carbon tetrachloride, and Di- and tetrachloroethylenes
Chernyshev,Komalenkova,Kapitova,Bykovchenko
, p. 1113 - 1116 (2007/10/03)
Gas-phase reactions of hexachlorodisilane with chloroalkanes (CHCl3 and CCl4) and chloroalkenes (ClCH=CHCl and Cl2C=CCl2) are studied. Dichlorosilylenes generated from Si2Cl6 insert into the C-Cl bonds in chloroalkanes; with chloroalkenes, insertion into the C-Cl bonds occurs along with cyclo-addition to the C=C bonds.
REACTIONS OF TRI- AND TETRA-CHLOROETHYLENES WITH TRICHLOROSILANE
Sheludyakov, V. D.,Zhun', V. I.,Lakhtin, V. G.,Shcherbinin, V. V.,Chernyshev, E. A.
, p. 1060 (2007/10/02)
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