69231-09-0Relevant articles and documents
A new, modular approach towards 2-(1-hydroxyalkyl)oxazolines, effective bidentate chiral ligands
Bauer, Michael,Kazmaier, Uli
, p. 2155 - 2158 (2006)
Addition of β-hydroxyisonitriles towards aldehydes gives rise to hydroxyalkyl oxazolines, an interesting class of bidentate chiral ligands. This concept allows a very easy ligand tuning and optimization of the ligand structure as illustrated in a first ex
Straightforward synthesis of chiral hydroxy isocyanides
Bauer, Michael,Kazmaier, Uli
experimental part, p. 2360 - 2366 (2009/09/05)
Various types of hydroxy isocyanides have been prepared from the corresponding amino alcohols. These hydroxy isocyanides are interesting building blocks for multicomponent reactions and the synthesis of (hydroxyalkyl) oxazoline ligands. The isocyanides ar
Ligand electronic effects in enantioselective diethylzinc additions
Casey, Mike,Smyth, Martin P.
, p. 102 - 106 (2007/10/03)
Enantiopure amino alcohols were converted into N-(2-hydroxyalkyl)formamides, which were converted into the chloro-alkylformamides. Treatment with phosphorus pentachloride and anilines, followed by basic workup, gave 2-unsubstituted imidazolines bearing va
