69257-64-3

Basic information

• Product Name: (1R,2S)-2-methoxy-2-phenylcyclohexanol
• CAS NO: 69257-64-3
• Molecular Formula: C₁₃H₁₈O₂
• Molecular Weight: 206.2808
• Mol File: 69257-64-3.mol
• Article Data: 4

Chemical Properties

• Boiling Point: 317.5°C at 760 mmHg
• Flash Point: 132.8°C
• Density: 1.07g/cm³
• Vapor Pressure: 0.000161mmHg at 25°C
• Refractive Index: 1.544
• CAS DataBase Reference: (1R,2S)-2-methoxy-2-phenylcyclohexanol(CAS DataBase Reference)
• NIST Chemistry Reference: (1R,2S)-2-methoxy-2-phenylcyclohexanol(69257-64-3)
• EPA Substance Registry System: (1R,2S)-2-methoxy-2-phenylcyclohexanol(69257-64-3)

Safety Data

• Hazardous Substances Data: 69257-64-3(Hazardous Substances Data)

Upstream product

• 67-56-1 methanol 
• 771-98-2 1-Phenylcyclohexene 
• 5775-23-5 1-phenylcyclohexene oxide 
• 4829-01-0 (-)-(1S,2S)-1-phenylcyclohex-1-ene oxide 

Downstream Products

• 69257-71-2 2-methoxy-2-phenyl-cyclohexanone 

Relevant articles and documents

Enantioselective protonation of samarium enolates derived from α- heterosubstituted ketones and lactone by SmI2-mediated reduction

SmI2-mediated reductive cleavage of α-heterosubstituents of α-alkyl or α-aryl ketones and lactone gave the corresponding 'thermodynamic samarium enolates'. Enantioselective protonation of the samarium enolates with C2- symmetric chiral diols afforded the corresponding ketones and lactone in moderate to high enantioselectivities.

Photochemical Reactions of Contact Charge-Transfer Pairs of 1-Arylcyclohexenes and Oxygen

Photoexcitation of contact charge-transfer (CCT) pairs of 1-arylcyclohexenes 1 (aryl: phenyl, 4-methylphenyl, and 4-methoxyphenyl) and oxygen in acetonitrile and benzene gave 1,2-epoxy-1-arylcyclohexanes 2 as major products together with 2-aryl-2-cyclohexen-1-ols and acetophenones 4.Similar irradiation of the CCT pairs in methanol/acetonitrile afforded mainly 2-aryl 2-cyclohexen-1-ones, and 4.The formation of these products can be explained by photoinduced electron transfer in the excited CCT pairs generating radical cations of 1 and superoxide anions.