692776-46-8

Basic information

• Product Name: (N(2,6-i-Pr₂C₆H₃)C(Me)CHC(Me)N(2,6-i-Pr₂C₆H₃))GeOH
• Synonyms: (N(2,6-i-Pr₂C₆H₃)C(Me)CHC(Me)N(2,6-i-Pr₂C₆H₃))GeOH
• CAS NO: 692776-46-8
• Molecular Weight: 507.255
• Mol File: 692776-46-8.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (N(2,6-i-Pr₂C₆H₃)C(Me)CHC(Me)N(2,6-i-Pr₂C₆H₃))GeOH(CAS DataBase Reference)
• NIST Chemistry Reference: (N(2,6-i-Pr₂C₆H₃)C(Me)CHC(Me)N(2,6-i-Pr₂C₆H₃))GeOH(692776-46-8)
• EPA Substance Registry System: (N(2,6-i-Pr₂C₆H₃)C(Me)CHC(Me)N(2,6-i-Pr₂C₆H₃))GeOH(692776-46-8)

Safety Data

• Hazardous Substances Data: 692776-46-8(Hazardous Substances Data)

Upstream product

• 334719-93-6 [C₃H(CH₃)2(N(2,6-diisopropylphenyl))2 chlorogermylene] 
• 7732-18-5 water 
• 908373-69-3 [((2,6-(i-Pr)2C₆H₃)NC(=CH₂)CH=C(Me)N(2,6-(i-Pr)2C₆H₃))Ge] 
• 98-80-6 phenylboronic acid 

Downstream Products

• 812646-94-9 [(CH(C(CH₃)NC₆H₃(CH(CH₃)2)2)2)Ge(S)(OH)] 
• 13463-40-6 iron pentacarbonyl 
• 887148-52-9 [(CH(C(CH₃)NC₆H₃(CH(CH₃)2)2)2)Ge(Se)(OH)] 

Relevant articles and documents

Preparation and structure of the first germanium(II) hydroxide: The congener of an unknown low-valent carbon analogue

Trapping HCl with an Arduengo-type carbene was the key to preparing and isolating the first germanium(II) hydroxide [LGeOH] (L = HC{(CMe)(2,6-iPr 2C6H3N)}2) by hydrolysis of the corresponding chloride. In the so

Stable compounds of composition LGe(II)R (R = OH, PhO, C6F 5O, PhCO2) prepared by nucleophilic addition reactions

The stable β-diketiminate germanium(II) compounds LGeR [L = HC(CMeNAr)2, Ar = 2,6-iPr2C6H3] (R = OTf, OH, PhO, C6F5O, PhCO2) are described. LGeOTf (2) is synthesized by salt metathesis reaction of LGeCl (1) with AgOTf and can be isolated as colorless crystals in 90% yield. Compound L'Ge (3) (L' = CH{(C=CH2)(CMe)(2,6-iPr2C6H3N) 2}) was obtained by treatment of LGeOTf (2) with 1 equiv of 1,3di-tert-butylimidazol-2-ylidene (NHC) in toluene. Reaction of 3 with H 2O, PhOH, C6F5OH, and PhCO2H, respectively, in toluene provided the germanium(II) compounds 4-7 in high yield. Compounds 2-7 were characterized by microanalysis and multinuclear NMR spectroscopy. Furthermore compounds 5, 6, and 7 are confirmed by X-ray structural analysis with the result that compounds 5,6, and 7 are monomeric and the germanium center resides in a trigonal-pyramidal environment.