6928-78-5Relevant articles and documents
FACILE MAGNESIATION OF CARBON BROENSTED ACIDS WITH ELECTROPHILIC, DONOR-FREE ALKYLMAGNESIUM COMPOUNDS
Eisch, John J.,Sanchez, Ramiro
, p. C27 - C31 (1985)
A solution of n-butyl (s-butyl)magnesium in an alkane reacts readily between 25 and 110 deg C with a series of carbon Broensted acids to produce the corresponding unsolvated diorganomagnesium derivatives in excellent yields.Such facile magnesiations provi
Ueber Metallalkyl- und -aryl-Verbindungen, XXVII. Darstellung und Kristallstruktur von Bis(phenylethinyl)bis(N,N,N',N'-tetramethylethylendiamin)magnesium, Mg(CCPh)2(tmeda)2
Schubert, Bernd,Behrens, Ulrich,Weiss, Erwin
, p. 2640 - 2643 (2007/10/02)
The title compound has been prepared from bis(phenylethynyl)magnesium and N,N,N',N'-tetramethylethylenediamine (tmeda) and investigated by X-ray diffraction methods (orthorhombic space group Cmcm, Z = 4, 696 reflections, R = 0.049).It represents a first e