69305-78-8

Basic information

• Product Name: diethyl 3,3-diethoxy-2-methylpropane-1,1-dicarboxylate
• Synonyms: diethyl 3,3-diethoxy-2-methylpropane-1,1-dicarboxylate
• CAS NO: 69305-78-8
• Molecular Weight: 290.357
• Mol File: 69305-78-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: diethyl 3,3-diethoxy-2-methylpropane-1,1-dicarboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: diethyl 3,3-diethoxy-2-methylpropane-1,1-dicarboxylate(69305-78-8)
• EPA Substance Registry System: diethyl 3,3-diethoxy-2-methylpropane-1,1-dicarboxylate(69305-78-8)

Safety Data

• Hazardous Substances Data: 69305-78-8(Hazardous Substances Data)

Upstream product

• 64-17-5 ethanol 
• 17085-88-0 diethyl propylidenemalonate 

Relevant articles and documents

Electrochemically induced oxidative rearrangement of alkylidenemalonates

Alkylidenemalonates capable of double bond migration being electrolyzed in methanol or ethanol in the presence of alkali metal halides in an undivided cell equipped with Fe cathode are transformed into 2-alkyl-3,3- dimethoxyalkane-1,2-dicarboxylates in 70-90% yield via electrochemically induced oxidative rearrangement. Acidification of the reaction mixture after the electrolysis leads to the formation of 2-alkyl-3-oxoalkane-1,1- dicarboxylates. In the case of isobutylidenemalonate, the electrolysis intermediate dimethyl 3,3-dimethyl-2-methoxy-cyclopropane-1,1-dicarboxylate was isolated in 70% yield.