69323-00-8Relevant articles and documents
Phenalenyl in a different role: Catalytic activation through the nonbonding molecular orbital
Raha Roy, Sudipta,Nijamudheen,Pariyar, Anand,Ghosh, Anup,Vardhanapu, Pavan K.,Mandal, Prasun K.,Datta, Ayan,Mandal, Swadhin K.
, p. 4307 - 4319 (2014)
We have demonstrated that the nonbonding molecular orbital (NBMO) of the phenalenyl (PLY) cation can be used as a Lewis acid catalyst for different organic transformations. Detailed computational and spectroscopic studies for the aminolysis reaction of ep
Fe(III) substituted Wells-Dawson type polyoxometalate: An efficient catalyst for ring opening of epoxides with aromatic amines
Aramesh,Yadollahi,Mirkhani
, p. 37 - 40 (2013/02/26)
Various β-aminoalcohols were prepared by the ring opening reaction of epoxides with aromatic amines in the presence of Fe(III) substituted Wells-Dawson type polyoxometalate, α2-[(n-C4H 9)4N]7P2/
Simple synthesis of β-acetoxy thiocyanates from oxiranes
Lukowska-Chojnacka, Edyta,Plenkiewicz, Jan
experimental part, p. 1999 - 2006 (2011/06/24)
A convenient and simple method for the preparation of previously unknown β-acetoxy thiocyanates by regioselective ring opening of the corresponding oxiranes with thiocyanate anion followed by acetylation is described. The shorter reaction times, better yields of the products, and easy workup are the advantages of this methodology.