6941-68-0

Basic information

• Product Name: prop-2-en-1-yl 4-methoxybenzoate
• Synonyms: Allyl 4-methoxybenzoate
• CAS NO: 6941-68-0
• Molecular Formula: C₁₁H₁₂O₃
• Molecular Weight: 192.2112
• Mol File: 6941-68-0.mol
• Article Data: 29

Chemical Properties

• Boiling Point: 289.6°C at 760 mmHg
• Flash Point: 117°C
• Density: 1.071g/cm³
• Vapor Pressure: 0.00218mmHg at 25°C
• Refractive Index: 1.51
• CAS DataBase Reference: prop-2-en-1-yl 4-methoxybenzoate(CAS DataBase Reference)
• NIST Chemistry Reference: prop-2-en-1-yl 4-methoxybenzoate(6941-68-0)
• EPA Substance Registry System: prop-2-en-1-yl 4-methoxybenzoate(6941-68-0)

Safety Data

• Hazardous Substances Data: 6941-68-0(Hazardous Substances Data)

Upstream product

• 123-11-5 4-methoxy-benzaldehyde 
• 107-18-6 allyl alcohol 
• 104-47-2 p-methoxybenzylnitrile 
• 14271-83-1 4-methoxybenzoyl cyanide 
• 106-95-6 allyl bromide 
• 100-09-4 4-methoxybenzoic acid 
• 121-98-2 methyl 4-methoxybenzoate 
• 52509-81-6 potassium 4-methoxybenzoate 
• 625-38-7 but-3-enoic acid 
• 24850-33-7 allyltributylstanane 
• 100-07-2 4-methoxy-benzoyl chloride 
• 556-56-9 allyl iodid 
• 107-05-1 3-chloroprop-1-ene 
• 80735-94-0 1-Phenyl-3-buten-1-ol 

Downstream Products

• 99859-52-6 4-methoxy-benzoic acid-(β,β'-dibromo-isopropyl ester) 
• 99859-53-7 4-methoxy-benzoic acid-(2,3-dibromo-propyl ester) 
• 123-38-6 propionaldehyde 
• 100-09-4 4-methoxybenzoic acid 
• 1236063-60-7 2-bromoallyl 4-methoxybenzoate 
• 1338089-99-8 C₁₁H₁₁BrO₃ 

Relevant articles and documents

Electron donor-acceptor (EDA)-complex enabled SF5Cl addition on alkenes and alkynes

A new method for the addition of SF5Cl on unsaturated compounds was developed, based on the use of an electron donor-acceptor (EDA)-complex and visible light irradiation. The reaction does not require the presence of oxygen to proceed, compared

Atmospheric Oxygen Mediated Radical Hydrothiolation of Alkenes

A mild, metal-free, atmospheric oxygen-mediated radical hydrothiolation of alkenes (and alkyne) is reported. A variety of sulfur containing motifs including alkanethiols, thiophenols and thioacids undergo an atmospheric oxygen-mediated radical hydrothiolation reaction with a plethora of alkenes in good yield with excellent functional group compatibility, typically with short reaction times to furnish a range of functionalized products. Biomolecules proved tolerant to the conditions and the procedure is robust and easily executable requiring no specialized equipment. Concise mechanistic studies confirm the process proceeds through radical intermediates in a thiol-ene reaction manifold. The methodology offers an efficient “green” approach for thiol-ene mediated “click” ligation and a milder alternative to thermally initiated hydrothiolation processes.

4-(4,6-Dimethoxy-1,3,5-triazin-2-yl)-4-methylmorpholinium Toluene-4-sulfonate (DMT/NMM/TsO?) Universal Coupling Reagent for Synthesis in Solution

4-(4,6-Dimethoxy-1,3,5-triazin-2-yl)-4-methylmorpholinium toluene-4-sulfonate (DMT/NMM/TsO?), a representative member of the inexpensive and environmentally-friendly N-triazinylammonium family of sulfonates, has been found to be a very effective coupling reagent for the synthesis of amides, esters and peptides in solution. This study confirms the usefulness of DMT/NMM/TsO? for peptide synthesis in solution, starting from Z-, Fmoc-, and Boc-protected substrates as well as unnatural building blocks. Peptide synthesis with DMT/NMM/TsO? produced high yields, with high crude product purity and low risk of racemization. In all cases, stoichiometric amounts of reagents were used and the standard synthetic procedure, without the need for time-consuming optimization stages or expensive chromatographic purification. DMT/NMM/TsO? was also found to be very useful for the synthesis of oligopeptides using a fragment coupling strategy.