6943-58-4

Basic information

• Product Name: 2-Propanol, 1-chloro-3-propoxy-
• Synonyms: 2-Propanol, 1-chloro-3-propoxy-
• CAS NO: 6943-58-4
• Molecular Formula: C₆H₁₃ClO₂
• Molecular Weight: 152.62
• Mol File: 6943-58-4.mol
• Article Data: 25

Chemical Properties

• Boiling Point: 210.74°C (rough estimate)
• Flash Point: 86.8°C
• Appearance: /
• Density: 1.0526
• Vapor Pressure: 0.0243mmHg at 25°C
• Refractive Index: 1.4378 (estimate)
• CAS DataBase Reference: 2-Propanol, 1-chloro-3-propoxy-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Propanol, 1-chloro-3-propoxy-(6943-58-4)
• EPA Substance Registry System: 2-Propanol, 1-chloro-3-propoxy-(6943-58-4)

Safety Data

• Hazardous Substances Data: 6943-58-4(Hazardous Substances Data)

Usage

Synthesis Reference(s)

Synthesis, p. 1152, 1994 DOI: 10.1055/s-1994-25661

InChI:InChI=1/C6H13ClO2/c1-2-3-9-5-6(8)4-7/h6,8H,2-5H2,1H3

Upstream product

• 71-23-8 propan-1-ol 
• 106-89-8 epichlorohydrin 

Downstream Products

• 10461-29-7 1-[2-(2-Methoxy-phenoxy)-ethylamino]-3-propoxy-propan-2-ol 
• 57429-06-8 1-chloro-3-propoxyacetone 
• 93155-18-1 2-Propyloxymethoxy-3-propyloxy-1-phenoxy-propan 
• 143503-49-5 (2-Heptyloxy-phenyl)-carbamic acid 2-azepan-1-yl-1-propoxymethyl-ethyl ester 
• 143503-47-3 (2-Hexyloxy-phenyl)-carbamic acid 2-azepan-1-yl-1-propoxymethyl-ethyl ester 
• 105920-54-5 (2-Heptyloxy-phenyl)-carbamic acid 2-piperidin-1-yl-1-propoxymethyl-ethyl ester 
• 143503-57-5 (3-Heptyloxy-phenyl)-carbamic acid 2-azepan-1-yl-1-propoxymethyl-ethyl ester 
• 143503-45-1 (2-Pentyloxy-phenyl)-carbamic acid 2-azepan-1-yl-1-propoxymethyl-ethyl ester 
• 105920-52-3 (2-Hexyloxy-phenyl)-carbamic acid 2-piperidin-1-yl-1-propoxymethyl-ethyl ester 
• 105919-56-0 (2-Heptyloxy-phenyl)-carbamic acid 1-propoxymethyl-2-pyrrolidin-1-yl-ethyl ester 
• 105920-62-5 (3-Heptyloxy-phenyl)-carbamic acid 2-piperidin-1-yl-1-propoxymethyl-ethyl ester 
• 143503-55-3 (3-Hexyloxy-phenyl)-carbamic acid 2-azepan-1-yl-1-propoxymethyl-ethyl ester 
• 143503-43-9 (2-Butoxy-phenyl)-carbamic acid 2-azepan-1-yl-1-propoxymethyl-ethyl ester 
• 105920-50-1 (2-Pentyloxy-phenyl)-carbamic acid 2-piperidin-1-yl-1-propoxymethyl-ethyl ester 

Relevant articles and documents

MBA-cross-linked poly(N-vinyl-2-pyrrolidone)/ferric chloride macromolecular coordination complex as a novel and recyclable Lewis acid catalyst: Synthesis, characterization, and performance toward for regioselective ring-opening alcoholysis of epoxides

A novel macromolecular-metal coordination complex, MBA-cross-linked PNVP/FeCl3 material was fabricated by immobilization of water intolerant ferric chloride onto the porous cross-linked poly(N-vinyl-2-pyrrolidone) carrier beads as a macromolecular ligand or carrier which was prepared by suspension free-radical copolymerization of N-vinyl-2-pyrrolidone (NVP) and N,N′-methylene bis-acrylamide (MBA) as a crosslinking agent in water. The obtained PNVP/FeCl3 was characterized by UV/vis and FT-IR spectroscopies, TGA, FE-SEM, EDX, and ICP techniques. This heterogenized version of ferric chloride is a convenient and safe alternative to highly water intolerant ferric chloride. The catalytic performance of (PNVP/FeCl3) as an efficient and recyclable polymeric Lewis acid catalyst was appropriately probed in the regio-and stereoselective nucleophilic ring opening of various epoxides with various alcohols in excellent yields with TOF up to 182.48 h?1 without generating any waste. The activity data indicate that this heterogeneous catalyst is very active and could be easily recovered, and reused at least six times without appreciable loss of activity indicating its stability under experimental conditions.

Mild and efficient ring opening of epoxides catalyzed by potassium dodecatungstocobaltate(III)

Efficient ring opening of epoxides under mild conditions is reported. Potassium dodecatungstocobaltate(III) trihydrate was used as an efficient catalyst for the alcoholysis and acetolysis of epoxides. Conversion of epoxides to thiiranes was also performed efficiently in the presence of this catalyst. Springer-Verlag 2005.

Synthesis of 1-alkoxy-3-N-succinimido-2-propanols

Procedures for preparing 1-alkoxy-3-chloro-2-propanols, with their subsequent transformation to 1-alkoxy-N-succinimido-2-propanols, were developed.