69447-34-3Relevant articles and documents
Iron(III) chloride-promoted cyclization of α,-alkynic tosylhydrazones with diselenides: Synthesis of 4-(arylselanyl)-1: H-pyrazoles
Ji, Shun-Jun,Li, Fang-Hui,Li, Jian,Wang, Shun-Yi,Yao, Hai-Feng
supporting information, p. 1987 - 1993 (2020/03/23)
A highly efficient iron(iii) chloride-promoted cyclization between α,-alkynic tosylhydrazones and diselenides to form a 4-(arylselanyl)-1H-pyrazole skeleton is studied. This reaction forms C-N and C-Se bonds in one step by utilizing inexpensive iron(iii) chloride instead of expensive transition metal additives. This strategy features easily synthesized substrates, mild reaction conditions and high tolerance to functional groups.