6947-35-9

Basic information

• Product Name: 4-methyl-N-(4-methylphenyl)-N-nitrosoaniline
• CAS NO: 6947-35-9
• Molecular Formula: C₁₄H₁₄N₂O
• Molecular Weight: 226.2738
• Mol File: 6947-35-9.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 402.3°C at 760 mmHg
• Flash Point: 197.1°C
• Density: 1.06g/cm³
• Vapor Pressure: 1.11E-06mmHg at 25°C
• Refractive Index: 1.568
• CAS DataBase Reference: 4-methyl-N-(4-methylphenyl)-N-nitrosoaniline(CAS DataBase Reference)
• NIST Chemistry Reference: 4-methyl-N-(4-methylphenyl)-N-nitrosoaniline(6947-35-9)
• EPA Substance Registry System: 4-methyl-N-(4-methylphenyl)-N-nitrosoaniline(6947-35-9)

Safety Data

• Hazardous Substances Data: 6947-35-9(Hazardous Substances Data)

Usage

General Description

4-methyl-N-(4-methylphenyl)-N-nitrosoaniline is a chemical compound with the molecular formula C14H14N2O2. It is a nitrosoaniline derivative with a nitroso functional group attached to the nitrogen atom of an aniline ring and two methyl groups attached to the nitrogen atom. 4-methyl-N-(4-methylphenyl)-N-nitrosoaniline is used as an intermediate in the synthesis of various organic compounds and can be found in some industrial processes. It is important to handle this chemical with care as it is a potential health hazard and can cause irritation to the skin, eyes, and respiratory system if not handled properly. Additionally, it may have harmful effects on aquatic organisms and the environment if not disposed of correctly.

Upstream product

• 3480-97-5 N–methyl–di–p–tolylamine 
• 108-88-3 toluene 
• 1807-53-0 tetrakis(4-methylphenyl)hydrazine 
• 620-93-9 di-p-tolylamine 

Downstream Products

• 861569-58-6 N'-phenyl-N,N-di-p-tolyl-hydrazine 
• 620-93-9 di-p-tolylamine 
• 31438-42-3 2,7-dimethyl-5,10-di-p-tolyl-5,10-dihydro-phenazine 
• 27758-60-7 1,1-bis(4-methylphenyl)hydrazine 
• 39606-59-2 1,2,1',2'-tetraphenyl-[3,3']azoindole 
• 4465-74-1 N-picryl-N',N'-di-p-tolyl-hydrazine 
• 6947-28-0 1,1-Di-p-tolyl-2-pikryl-hydrazin 
• 1227476-15-4 Azobenzene 
• 92255-59-9 1,1-bis(p-anisyl)hydrazine 
• 31438-18-3 (2-nitro-4-methylphenyl)-4-methylphenylamine 

Relevant articles and documents

Highly selective sp3 C-N bond activation of tertiary anilines modulated by steric and thermodynamic factors

A highly selective sp3 C-N cleavage of tertiary anilines was achieved using the TBN/TEMPO catalyst system. When N,N-diaklylanilines (alkyl, benzyl) were employed, the N-CH3 bond was selectively cleaved via radical C-H activation. Moreover, when the allyl group was installed, totally reverse selectivity was observed. It is worth noting that the solvent effect is also crucial to obtain high reaction efficiency and selectivity.

Groups 5 and 6 terminal hydrazido(2-) complexes: Nβ substituent effects on ligand-to-metal charge-transfer energies and oxidation states

Brightly colored terminal hydrazido(2-) (dme)MCl3(NNR 2) (dme = 1,2-dimethoxyethane; M = Nb, Ta; R = alkyl, aryl) or (MeCN)WCl4(NNR2) complexes have been synthesized and characterized. Perturbing the electronic environment of the β (NR 2) nitrogen affects the energy of the lowest-energy charge-transfer (CT) transition in these complexes. For group 5 complexes, increasing the energy of the Nβ lone pair decreases the ligand-to-metal CT (LMCT) energy, except for electron-rich niobium dialkylhydrazides, which pyramidalize Nβ in order to reduce the overlap between the Nb=N α π bond and the Nβ lone pair. For W complexes, increasing the energy of Nβ eventually leads to reduction from formally [WVI≡N-NR2] with a hydrazido(2-) ligand to [WIV=N=NR2] with a neutral 1,1-diazene ligand. The photophysical properties of these complexes highlight the potential redox noninnocence of hydrazido ligands, which could lead to ligand- and/or metal-based redox chemistry in early transition metal derivatives.