69503-86-2Relevant articles and documents
High yielding alkylations of unactivated sp3 and sp2 centres with alkyl-9-BBN reagents using an NHC-based catalyst: Pd-PEPPSI-IPr
Valente, Cory,Baglione, Sylvia,Candito, David,O'Brien, Christopher J.,Organ, Michael G.
, p. 735 - 737 (2008/09/17)
High yielding, room temperature cross couplings of unactivated alkyl bromides and aryl bromides/chlorides with alkyl-9-BBN reagents has been achieved using an NHC-based catalyst (Pd-PEPPSI-IPr) via a general, functional-group tolerant and easily implemented protocol. The Royal Society of Chemistry.
Phosphaadamantanes as ligands for palladium catalyzed cross-coupling chemistry: Library synthesis, characterization, and screening in the Suzuki coupling of alkyl halides and tosylates containing β-hydrogens with boronic acids and alkylboranes
Brenstrum, Tim,Gerristma, David A.,Adjabeng, George M.,Frampton, Christopher S.,Britten, James,Robertson, Alan J.,McNulty, James,Capretta, Alfredo
, p. 7635 - 7639 (2007/10/03)
A 15-member library of phosphaadamantane ligands has been prepared via P-arylation of 1,3,5,7-tetramethyl-2,4,8-trioxa-6-phosphaadamantane. Screening of this tertiary phosphine collection has allowed for the rapid determination of the most suitable ligand, specifically 1,3,5,7-tetramethyl-6-(2,4- dimethoxyphenyl)-2,4,8-trioxa-6-phosphaadamantane, for facilitating Suzuki-type couplings of alkyl halides or tosylates containing β-hydrogens with either boronic acids or alkylboranes.
Room-temperature alkyl-alkyl Suzuki cross-coupling of alkyl bromides that possess β hydrogens [1]
Netherton,Dai,Neuschuetz,Fu
, p. 10099 - 10100 (2007/10/03)
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