69555-18-6Relevant articles and documents
Design and synthesis of a s-triazene based asymmetric organocatalyst and its application in enantioselective alkylation
Mangawa, Shrawan K.,Singh, Ashawani K.,Awasthi, Satish K.
, p. 61144 - 61147 (2015/08/03)
A very efficient chiral organocatalyst was prepared from the readily available cyanuric chloride. The asymmetric catalyst exhibited a highly enantioselective catalytic performance for the alkylation of a glycinate Schiff base, which provides a useful procedure for the enantioselective synthesis of structurally diverse natural and unnatural α-alkyl-α-amino acids.
Palladium-catalyzed decarboxylative benzylation of diphenylglycinate lmines
Fields, Wendy H.,Chruma, Jason J.
supporting information; experimental part, p. 316 - 319 (2010/03/24)
(Figure presented) General reaction conditions for the Pd-catalyzed decarboxylative benzylation of benzyl diphenylglycinate lmines are described. The overall procedure requires a simple catalyst/ligand combination to form a new Csp3-Csp3 bond. Microwave Irradiation greatly accelerated the transformation. Moreover, various heteroaromatlc moieties are tolerated in both the imine and ester components.
Novel potential enantioselective phase transfer catalysts based on lupinine
Dehmlow, Eckehard Volker,Klauck, Robert,Neumann, Beate,Stammler, Hans-Georg
experimental part, p. 572 - 575 (2011/10/09)
Ten N-alkylated lupininium derivatives 5-8 were prepared as potential enantioselective phase transfer catalysts. Compounds 5a-d, 6a-d contain four asymmetric centers (including one in the side chain) with known configuration resting on an X-ray structure.