69563-05-9

Basic information

• Product Name: (3-Trifluoromethyl-phenyl)-trimethylsilanyl-amine
• Synonyms: (3-Trifluoromethyl-phenyl)-trimethylsilanyl-amine
• CAS NO: 69563-05-9
• Molecular Weight: 233.309
• Mol File: 69563-05-9.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (3-Trifluoromethyl-phenyl)-trimethylsilanyl-amine(CAS DataBase Reference)
• NIST Chemistry Reference: (3-Trifluoromethyl-phenyl)-trimethylsilanyl-amine(69563-05-9)
• EPA Substance Registry System: (3-Trifluoromethyl-phenyl)-trimethylsilanyl-amine(69563-05-9)

Safety Data

• Hazardous Substances Data: 69563-05-9(Hazardous Substances Data)

Upstream product

• 75-77-4 chloro-trimethyl-silane 
• 98-16-8 3-trifluoromethylaniline 
• 999-97-3 1,1,1,3,3,3-hexamethyl-disilazane 

Downstream Products

• 329-01-1 1-isocyanato-3-trifluoromethyl-benzene 
• 403-96-3 1,3-bis(m-α,α,α-trifluorotolyl)urea 
• 15386-85-3 3-oxo-3-{[3-(trifluoromethyl)phenyl]amino}propanoic acid 
• 127633-93-6 Cyano-[1-methyl-5-(3-trifluoromethyl-phenylamino)-pyrrolidin-(2Z)-ylidene]-acetic acid methyl ester 
• 67-64-1 acetone 

Relevant articles and documents

Stoichiometric Reactions of CO2 and Indium-Silylamides and Catalytic Synthesis of Ureas

The indium compounds In(N(SiMe3)2)2Cl?THF (2) and In(N(SiMe3)2)Cl2?(THF)n (3) were shown to react with CO2 to give [(Me3Si)2N)InX(μ-OSiMe3)]2 (X=N(SiMe3)2 4, Cl 5). 0.05–2.0 mol % of the species 3 acts as a pre-catalyst for the conversion of aryl and alkyl silylamines under CO2 (2–3 atm) to give the corresponding ureas in 70–99 % yields. A proposed mechanism is supported by experimental and computational data.

Selective electrochemical synthesis and reactivity of functional benzylic fluorosilylsynthons

Electrochemical reductive silylation of meta-(trifluoromethyl)arenes by the sacrificial anode technique selectively led to meta-trimethylsilyldifluoromethylarenes (ArCF2TMS), in the presence of an excess of TMSCl and in a THF/cosolvent mixture