6962-31-8

Basic information

• Product Name: pyrrolidine-1-carbodithioic acid - pyrrolidine (1:1)
• CAS NO: 6962-31-8
• Molecular Formula: C₄H₁₀N*C₅H₈NS₂
• Molecular Weight: 218.3826
• Mol File: 6962-31-8.mol
• Article Data: 5

Chemical Properties

• Boiling Point: 199.7°C at 760 mmHg
• Flash Point: 74.6°C
• Vapor Pressure: 0.337mmHg at 25°C
• CAS DataBase Reference: pyrrolidine-1-carbodithioic acid - pyrrolidine (1:1)(CAS DataBase Reference)
• NIST Chemistry Reference: pyrrolidine-1-carbodithioic acid - pyrrolidine (1:1)(6962-31-8)
• EPA Substance Registry System: pyrrolidine-1-carbodithioic acid - pyrrolidine (1:1)(6962-31-8)

Safety Data

• Hazardous Substances Data: 6962-31-8(Hazardous Substances Data)

Upstream product

• 123-75-1 pyrrolidine 
• 75-15-0 carbon disulfide 

Downstream Products

• 64531-48-2 3,5-Dinitro-benzoic acid; compound with naphthalene 
• 76539-67-8 4-Dimethylamino-6,6-dimethyl-5,6-dihydro-thiopyran-2-thione 
• 76539-81-6 6-(3,4-Dimethoxy-phenyl)-4-pyrrolidin-1-yl-5,6-dihydro-thiopyran-2-thione 
• 112051-09-9 Pyrrolidine-1-carbodithioic acid 2-[(E)-hydroxyimino]-2-phenyl-ethyl ester 
• 112051-10-2 Pyrrolidine-1-carbodithioic acid 2-[(E)-hydroxyimino]-2-phenyl-ethyl ester 
• 112051-09-9 Pyrrolidine-1-carbodithioic acid 2-[(Z)-hydroxyimino]-2-phenyl-ethyl ester 
• 76539-76-9 6-Phenyl-4-pyrrolidin-1-yl-5,6-dihydro-thiopyran-2-thione 
• 76539-89-4 5-Methyl-6-phenyl-4-pyrrolidin-1-yl-5,6-dihydro-thiopyran-2-thione 
• 98121-67-6 2-oxo-2-phenylethyl pyrrolidine-1-carbodithioate 
• 98121-69-8 2-(4-bromophenyl)-2-oxoethyl pyrrolidine-1-carbodithioate 
• 98121-68-7 2-(4-nitrophenyl)-2-oxoethyl pyrrolidine-1-carbodithioate 
• 1391998-36-9 C₁₉H₂₆N₂S₄ 
• 1391998-51-8 C₁₇H₂₂N₂S₄ 
• 1391998-46-1 C₁₇H₂₁ClN₂S₄ 

Relevant articles and documents

Cu-mediated one-pot three-component synthesis of 3-N-substituted 1,4,2-benzodithiazine 1,1-dioxide derivatives

A novel and efficient copper-catalyzed one-pot procedure for the synthesis of 3-N-substituted 1,4,2-benzodithiazine 1,1-dioxide derivatives from 2-halobenzenesulfonamides, amines and CS2 is described. The reaction proceeds through Ullmann-type S-arylation, intramolecular addition of NH2 with C[dbnd]S and dehydrosulfide, which provides a new and useful strategy for construction of cyclic aromatic sulfonamides.

Cyclic ammonium salts of dithiocarbamic acid: stable alternative reagents for the synthesis of S-alkyl carbodithioates from organyl thiocyanates in water

ABSTRACT: Carbodithioate esters are important functional organosulfur compounds widely used in diverse fields such as pharmaceuticals, agrochemicals and material sciences. Common preparative methods include reaction of alkyl halides, carbon disulfide and bases under both metal-free and metal-catalyzed conditions. However, organyl thiocyanates have not been previously explored, possibly because of their conversion to organyl disulfides under basic conditions. Here, we report an efficient and practical method for the preparation of libraries of carbodithioate esters from organyl thiocyanates by reacting with cyclic amine-based dithiocarbamic acid salts in water. The protocol is found to be applicable in general to various thiocyanates such as benzyl/aroyl methyl/cinnamyl and so on. Other notable features include no by-products such as disulfides, metal- and alkali-free, aqueous conditions, and finally easy and near-quantitative formation of cyclic amine-based dithiocarbamic acid salt as a stable alternative reagent.

Radioprotective activity of new dithiocarbamic acid salts

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