69689-99-2

Basic information

• Product Name: 3-[(4-methoxyphenyl)amino]-3-phenylprop-2-enenitrile
• CAS NO: 69689-99-2
• Molecular Formula: C₁₆H₁₄N₂O
• Molecular Weight: 250.2952
• Mol File: 69689-99-2.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 423.7°C at 760 mmHg
• Flash Point: 210.1°C
• Density: 1.164g/cm³
• Vapor Pressure: 2.18E-07mmHg at 25°C
• Refractive Index: 1.63
• CAS DataBase Reference: 3-[(4-methoxyphenyl)amino]-3-phenylprop-2-enenitrile(CAS DataBase Reference)
• NIST Chemistry Reference: 3-[(4-methoxyphenyl)amino]-3-phenylprop-2-enenitrile(69689-99-2)
• EPA Substance Registry System: 3-[(4-methoxyphenyl)amino]-3-phenylprop-2-enenitrile(69689-99-2)

Safety Data

• Hazardous Substances Data: 69689-99-2(Hazardous Substances Data)

Upstream product

• 614-16-4 Benzoylacetonitrile 
• 104-94-9 4-methoxy-aniline 
• 935-02-4 3-Phenyl-2-propynonitrile 

Downstream Products

• 1088711-61-8 (S)-3-((4-methoxyphenyl)amino)-3-phenylpropanenitrile 
• 101290-91-9 5-methoxy-2-phenyl-1H-indole-3-carbonitrile 
• 72694-06-5 (Z)-2-Cyano-3-(4-methoxy-phenylamino)-3-phenyl-dithioacrylic acid ethyl ester 

Relevant articles and documents

PIDA-mediated oxidative C-C bond formation: Novel synthesis of indoles from n-aryl enamines

A variety of functionalized indoles were synthesized from N-aryl enamines via PIDA-mediated oxidative carbon-carbon bond formation. The features of the present reaction include facilitative preparation of substrates 2, good functional group tolerance, and mild reaction conditions without transition metals.

Addition of diazoacetonitrile to N-benzylidene-anilines. Synthesis and decomposition of 4-cyano-1,5-diaryl,Δ2-1,2,3-triazolines

Addition of diazoacetonitrile to para-substituted N-benzilidene-anilines has been studied. The addition is easier if the substituent is an electrodonating group. Products obtained are Δ2-1,2,3-triazolines or aziridnes, and enamines resulting from the decomposition of the triazolines with migration of the 5-aryl substituent. Decomposition of the triazolines under various conditions has also been studied.