697299-24-4

Basic information

• Product Name: [(PhB(CH2P(i-Pr2)3)Ir(H)(η3-C8H13)]
• CAS NO: 697299-24-4
• Molecular Weight: 783.869
• Mol File: 697299-24-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [(PhB(CH2P(i-Pr2)3)Ir(H)(η3-C8H13)](CAS DataBase Reference)
• NIST Chemistry Reference: [(PhB(CH2P(i-Pr2)3)Ir(H)(η3-C8H13)](697299-24-4)
• EPA Substance Registry System: [(PhB(CH2P(i-Pr2)3)Ir(H)(η3-C8H13)](697299-24-4)

Safety Data

• Hazardous Substances Data: 697299-24-4(Hazardous Substances Data)

Upstream product

• 627090-51-1 [Li(tetrahydrofuran)PhB(CH₂P(i)Pr₂)3] 

Downstream Products

• 697299-27-7 [(C₆H₅B(CH₂P(CH(CH₃)2)2)3)IrH₃(SiH(C₆H₅)2)] 
• 697299-30-2 [(C₆H₅B(CH₂P(CH(CH₃)2)2)3)IrH₂(CO)] 
• 697299-26-6 [(C₆H₅B(CH₂P(CH(CH₃)2)2)3)IrH₃(SiH(C₂H₅)2)] 
• 697299-29-9 [(C₆H₅B(CH₂P(CH(CH₃)2)2)3)IrH₂(PH₂(C₆H₁₁))] 

Relevant articles and documents

Coordination chemistry and reactivity of new zwitterionic rhodium and iridium complexes featuring the tripodal phosphine ligand [PhB(CH 2PiPr2)3]-. Activation of H-H, Si-H, and ligand B-C bonds

The synthesis, characterization, and reactivity of zwitterionic rhodium and iridium complexes were carried out. The zwitterionic rhodium and iridium complexes contains tris(phosphino)borate ligand [PhB(CH2P iPr2)3] -([PhBP3 ']-). The allyl complexes were prepared by reaction of [PhBP3']Li(THF) with the corresponding [(alkene) 2IrCl)2 complex. It was stated that the ligand B-C bond activation was shown to be a facile reaction pathway for [PhBP3 ']Rh complexes.