69790-20-1

Basic information

• Product Name: 3-Heptanone, 7-phenyl-
• CAS NO: 69790-20-1
• Molecular Formula: C13H18O
• Molecular Weight: 190.285
• Mol File: 69790-20-1.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: 3-Heptanone, 7-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Heptanone, 7-phenyl-(69790-20-1)
• EPA Substance Registry System: 3-Heptanone, 7-phenyl-(69790-20-1)

Safety Data

• Hazardous Substances Data: 69790-20-1(Hazardous Substances Data)

Upstream product

• 100-42-5 styrene 
• 1629-58-9 4-penten-3-one 
• 80473-65-0 dilithium divinylcyanocuprate 
• 925-90-6 ethylmagnesium bromide 
• 79-03-8 propionyl chloride 
• 27152-04-1 (4-phenylbutyl)magnesium bromide 
• 2270-20-4 5-Phenylpentanoic acid 

Downstream Products

• 622-21-9 dicinnamylideneacetone 
• 60012-63-7 7-phenylheptan-3-ol 

Relevant articles and documents

Hemilabile Benzyl Ether Enables Γ-C(sp3)-H Carbonylation and Olefination of Alcohols

Pd-catalyzed C(sp3)-H activation of alcohol typically shows β-selectivity due to the required distance between the chelating atom in the attached directing group and the targeted C-H bonds. Herein we report the design of a hemilabile directing group which exploits the chelation of a readily removable benzyl ether moiety to direct Γ- or δ-C-H carbonylation and olefination of alcohols. The utility of this approach is also demonstrated in the late-stage C-H functionalization of β-estradiol to rapidly prepare desired analogues that required multi-step syntheses with classical methods.

Iminyl Radical-Triggered Intermolecular Distal C(sp3)-H Heteroarylation via 1,5-Hydrogen-Atom Transfer (HAT) Cascade

An efficient iron-catalyzed intermolecular remote C(sp3)-H heteroarylation of alkyl ketones has been developed via an iminyl radical-triggered 1,5-hydrogen-atom transfer (HAT) cascade. This protocol was amenable to a wide variety of alkyl ketones and heteroaryls, thus providing a straightforward method for the late-stage functionalization of alkylketones and heteroaryls.

Reactions of acylzirconocene chloride with nucleophiles: Bimodal reactivity at β- and acyl carbons of α,β-unsaturated acylzirconocene chloride

Reactions of α,β-unsaturated acylzirconocene chloride with nucleophiles showed novel bimodal reactivity at the β- and acyl carbons depending upon the nucleophile employed, and the formation of ketone α,β-dianionic species was also observed. (C) 2000 Elsev