69838-86-4Relevant articles and documents
Unraveling the Dynamic Network in the Reactions of an Alkyl Aryl Ether Catalyzed by Ni/γ-Al2O3 in 2-Propanol
Qi, Long,Chamas, Ali,Jones, Zachary R.,Walter, Eric D.,Hoyt, David W.,Washton, Nancy M.,Scott, Susannah L.
, p. 17370 - 17381 (2019/11/03)
The reductive cleavage of aryl ether linkages is a key step in the disassembly of lignin to its monolignol components, where selectivity is determined by the kinetics of multiple parallel and consecutive liquid-phase reactions. Triphasic hydrogenolysis of
Shapes of dendrimers from rotational-echo double-resonance NMR
Wooley, Karen L.,Klug, Christopher A.,Tasaki, Kenzabu,Schaefer, Jacob
, p. 53 - 58 (2007/10/03)
The solid-state shape, size, and intermolecular packing of a fifth-generation dendritic macromolecule were determined by a combination of site-specific stable-isotope-labeling, rotational-echo double-resonance (REDOR) NMR and distance-constrained molecula
Degenerate Carbon Skeleton Isomerization of the Cyclopentyl Cation in the Gas Phase. Experimental and Theoretical Evidence for the Existence of a Pyramidal C5H9(+) Cation as an Intermediate in the Unimolecular Ethylene Elimination
Franke, Wilfried,Schwarz, Helmut,Thies, Helga,Chandrasekhar, Jayaraman,Raque' Schleyer, Paul von,et al.
, p. 2808 - 2824 (2007/10/02)
The investigation of 13C2-labelled isotopomeric bromocyclopentanes (5a, b), cyclobutylmethyl bromide (6a) and 5-bromo-1-pentenes (7a, b) clearly demonstrates, that unimolecular ethylene loss from the gaseous + ions generated from both the cyclic and acyclic precursors is preceded by complete carbon scrambling.Whereas the degenerate isomerization 8a 8b can, in principle, proceed either via the bisected cyclobutylmethyl cation 9 or via the non-classical, pyramidal cation 3, the MINDO/3 calculations reveal, that ethylene loss from C5H9+ involves 3 as an intermediate.From 3 a transition state is reached which can be regarded as a partially opened cyclopropyl cation "solvated" by interaction with C2H4.Descriptions of the syntheses of the 13C2-labelled bromides are given.