700378-37-6Relevant articles and documents
β-sih-containing tris(silazido) rare-earth complexes as homogeneous and grafted single-site catalyst precursors for hydroamination
Eedugurala, Naresh,Wang, Zhuoran,Yan, Kaking,Boteju, Kasuni C.,Chaudhary, Umesh,Kobayashi, Takeshi,Ellern, Arkady,Slowing, Igor I.,Pruski, Marek,Sadow, Aaron D.
supporting information, p. 1142 - 1153 (2017/12/08)
A series of homoleptic rare-earth silazido compounds and their silica-grafted derivatives were prepared to compare spectroscopic and catalytic features under homogeneous and interfacial conditions. Trivalent tris-(silazido) compounds Ln{N(SiHMe2/sub
New highly active heteroscorpionate-containing lutetium catalysts for the hydroamination of aminoalkenes: Isolation and structural characterization of a dipyrrolidinide-lutetium complex
Otero, Antonio,Lara-Sanchez, Agustin,Najera, Carmen,Fernandez-Baeza, Juan,Marquez-Segovia, Isabel,Castro-Osma, Jose Antonio,Martinez, Javier,Sanchez-Barba, Luis F.,Rodriguez, Ana M.
scheme or table, p. 2244 - 2255 (2012/06/04)
The reactions of the hybrid scorpionate/cyclopentadiene compounds, as a mixture of regioisomers-1-[2,2-bis(3,5-dimethylpyrazol-1-yl)-1,1-diphenylethyl]- 1,3-cyclopentadiene and 2-[2,2-bis(3,5-dimethylpyrazol-1-yl)-1,1-diphenylethyl]- 1,3-cyclopentadiene (
Highly efficient, base-catalysed, intramolecular hydroamination of non-activated olefins
Quinet, Coralie,Jourdain, Pierre,Hermans, Christophe,Ates, Ali,Lucas, Isabelle,Markó, István E.
, p. 1077 - 1087 (2008/09/17)
The intramolecular hydroamination of a large variety of non-activated alkenes can be efficiently catalysed by small amounts of lithium bases, providing smoothly and in high yields the corresponding five- and six-membered ring heterocycles. Fused and bridged bicyclic amines, of varying ring sizes, can be readily prepared either by a sequential hydroamination process or by a tandem, double addition reaction.