70113-68-7

Basic information

• Product Name: 2-(3-Methoxy-2,2,3-trimethyl-butyryl)-N-methyl-benzamide
• CAS NO: 70113-68-7
• Molecular Weight: 277.364
• Mol File: 70113-68-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-(3-Methoxy-2,2,3-trimethyl-butyryl)-N-methyl-benzamide(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(3-Methoxy-2,2,3-trimethyl-butyryl)-N-methyl-benzamide(70113-68-7)
• EPA Substance Registry System: 2-(3-Methoxy-2,2,3-trimethyl-butyryl)-N-methyl-benzamide(70113-68-7)

Safety Data

• Hazardous Substances Data: 70113-68-7(Hazardous Substances Data)

Upstream product

• 67-56-1 methanol 
• 550-44-7 N-methylphthalimide 
• 563-79-1 2,3-Dimethyl-2-butene 

Relevant articles and documents

Competitive Photochemical ?2 + ?2 Addition and Electron Transfer in the N-Methylphthalimide-Alkene System

N-Methylphthalimide (NMP) undergoes a pair of competing photochemical reactions in the presence of alkenes.In one of these reactions the alkene adds to the C(O)-N bond of NMP in a concerted ?2 + ?2 process that ultimately leads to 2-benzazepine-1,5-diones (5).A competing electron-transfer process results in the formation of a radical cation-radical anion pair which can be efficiently trapped in alcohols solvents such as 4.The regiochemistry of these products is consistent with expectations for addition of an alcohol to a radical cation.Calculations usingthe Weller equation accurately predict when electron transfer should dominate the ?2 + ?2 process, when the ?2 + ?2 process should dominate the electron transfer process, and when the two should be directly competitive.Product studies on the formation of 4 and 5 for various alkenes in methanol solution are entirely consistent with this hypothesis.