702-81-8Relevant articles and documents
One-pot synthesis of cage alcohols
Klimochkin, Yu. N.,Yudashkin,Zhilkina,Ivleva,Moiseev,Oshis, Ya. F.
, p. 971 - 976 (2017/09/07)
An efficient one-pot procedure has been developed for the synthesis of cage alcohols with hydroxy groups in the bridgehead positions. The procedure includes initial nitroxylation with nitric acid or a mixture of nitric acid with acetic acid and subsequent hydrolysis in the presence of urea.
Synthesis of hydroxy derivatives from adamantanecarboxylic acids in the system MnO2–H2SO4
Ivleva,Gavrilova,Klimochkin, Yu. N.
, p. 785 - 790 (2016/07/30)
A convenient procedure has been developed for the synthesis of mono- and dihydric cage alcohols from adamantanecarboxylic acids and their esters using the MnO2–H2SO4system. The reaction at elevated temperature involved both decarboxylation and decarbonylation of the initial acid or ester.
Formation of adamantan-1-ols by the reactions of adamantanes with 2,3-dichloro-5,6-dicyano-p-benzoquinone (DDQ) in trifluoromethanesulfonic acid
Tanemura,Suzuki,Nishida,Satsumabayashi,Horaguchi
, p. 3230 - 3231 (2007/10/03)
Adamantanes were treated with DDQ in trifluoromethanesulfonic acid followed by hydrolysis to give adamantan-1-ols in good yields.