70238-24-3

Basic information

• Product Name: Benzene, 1-[[3,7-dimethyl-6-(phenylthio)-2,7-octadienyl]sulfonyl]-4-methyl-, (E)-
• CAS NO: 70238-24-3
• Molecular Formula: C23H28O2S2
• Molecular Weight: 400.606
• Mol File: 70238-24-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Benzene, 1-[[3,7-dimethyl-6-(phenylthio)-2,7-octadienyl]sulfonyl]-4-methyl-, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-[[3,7-dimethyl-6-(phenylthio)-2,7-octadienyl]sulfonyl]-4-methyl-, (E)-(70238-24-3)
• EPA Substance Registry System: Benzene, 1-[[3,7-dimethyl-6-(phenylthio)-2,7-octadienyl]sulfonyl]-4-methyl-, (E)-(70238-24-3)

Safety Data

• Hazardous Substances Data: 70238-24-3(Hazardous Substances Data)

Upstream product

• 53254-60-7 3,7-dimethyl-1-(p-toluenesulfonyl)-2(E),6-octadiene 
• 931-59-9 benzenesulfenyl chloride 
• 70473-45-9 (E)-2,6-Dimethyl-3-phenylsulfanyl-8-(toluene-4-sulfonyl)-oct-6-en-2-ol 

Downstream Products

• 94852-98-9 (2E,6E)-2,6-Dimethyl-8-(toluene-4-sulfonyl)-octa-2,6-dienal 
• 70238-35-6 (2E,6E)-3,7-dimethyl-1-(4-methylbenzenesulfonyl)-2,6-octadien-8-ol 
• 81491-10-3 1-((E)-6-Benzenesulfinyl-3,7-dimethyl-octa-2,7-diene-1-sulfonyl)-4-methyl-benzene 

Relevant articles and documents

FACILE FUNCTIONALIZATION OF THE ISOPROPYLIDENE TERMINUS OF ACYCLIC MONOTERPENES BY WAY OF BENZENESULFENYL CHLORIDE ADDITION

Highly site- and regioselective terminal functionalizations of acyclic monoterpenes 1 via benzenesulfenyl chloride addition followed by hydrolysis assisted by silica gel, dehydrochlorination under neutral or weakly basic condition, or dehydrochlorination by strongly basic treatment respectively providing β-hydroxy sulfides 3, terminal methallylic sulfides 4, or vinylsulfides 5 are developed.Conversion of 4 to terminal trans-allylic alcohols 10 via sulfoxides 9 by the Evans procedure is also described.