70372-38-2

Basic information

• Product Name: 1-(1,2-dithiocyanatoethyl)-4-methylbenzene
• Synonyms: 1-(1,2-dithiocyanatoethyl)-4-methylbenzene
• CAS NO: 70372-38-2
• Molecular Weight: 234.346
• Mol File: 70372-38-2.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: 1-(1,2-dithiocyanatoethyl)-4-methylbenzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(1,2-dithiocyanatoethyl)-4-methylbenzene(70372-38-2)
• EPA Substance Registry System: 1-(1,2-dithiocyanatoethyl)-4-methylbenzene(70372-38-2)

Safety Data

• Hazardous Substances Data: 70372-38-2(Hazardous Substances Data)

Upstream product

• 622-97-9 1-ethenyl-4-methylbenzene 
• 333-20-0 potassium thioacyanate 
• 2051-59-4 6-Chloro-chromen-2-one 
• 540-72-7 sodium thiocyanide 
• 1147550-11-5 ammonium thiocyanate 
• 505-14-6 thiocyanogen 
• 64-19-7 acetic acid 

Relevant articles and documents

Peroxodisulfate-assisted three-component benzylation of coumarins with styrenes and KSCN: a transition-metal-free approach for the synthesis of 3-(1-aryl-2-thiocyanatoethyl)-2H-chromen-2-one in ethyl lactate

Peroxodisulfate-assisted three-component benzylation of coumarins with styrenes and KSCN to 3-(1-aryl-2-thiocyanatoethyl)-2H-chromen-2-one is reported for the first time. This reaction proceedsviathe consecutive addition of the SCN radical to styrenes followed by the addition of the resultant substituted-benzylic radical to the C3-position of coumarin derivatives. In contrast to previous approaches that normally require transition-metal catalysis, toxic volatile organic solvents, bases and elevated temperature, the present strategy of benzylation of coumarins is transition-metal-free and base-free, and applicable under ambient conditions with ethyl lactate as a green medium.

Ferric(III) chloride-promoted efficient thiocyanation of arylalkenes: A facile synthesis of dithiocyanates

Anhydrous FeCl3 oxidizes potassium thiocyanate to the corresponding radical and promotes subsequent addition to nucleophilic olefins to produce dithiocyanate derivatives under mild conditions with high efficiency. Excellent yields and chemosele

A very efficient Cerium (IV) ammonium nitrate (CAN) mediated thiocyanation of aralkenes: Formation of dithiocyanates

A facile dithiocyanation of aralkenes mediated by Cerium (IV) ammonium nitrate is described.