70424-35-0

Basic information

• Product Name: Silane, trimethyl[[1-(2-phenylethyl)-1-propenyl]oxy]-, (E)-
• CAS NO: 70424-35-0
• Molecular Formula: C14H22OSi
• Molecular Weight: 234.414
• Mol File: 70424-35-0.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Silane, trimethyl[[1-(2-phenylethyl)-1-propenyl]oxy]-, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, trimethyl[[1-(2-phenylethyl)-1-propenyl]oxy]-, (E)-(70424-35-0)
• EPA Substance Registry System: Silane, trimethyl[[1-(2-phenylethyl)-1-propenyl]oxy]-, (E)-(70424-35-0)

Safety Data

• Hazardous Substances Data: 70424-35-0(Hazardous Substances Data)

Upstream product

• 75-77-4 chloro-trimethyl-silane 
• 97394-41-7 S-(4-nitrophenyl) 3-phenylpropanethioate 
• 88257-48-1 5-Phenyl-2-trimethylsilanyl-pent-1-en-3-ol 
• 72551-26-9 5-phenyl-3-(trimethylsilyl)-1-penten-3-ol 
• 61157-31-1 3-phenylpropionyltrimethylsilane 

Relevant articles and documents

A FACILE SYNTHESIS OF α-TRIMETHYLSILYL KETONES AND THEIR REGIOSPECIFIC REARRANGEMENT TO TRIMETHYLSILY ENOL ETHERS

The rhodium catlyzed isomerization of β-trimethylsilylallyl alcohols has been successfully applied for the stepwise and selective synthesis of α-trimethylsilyl ketones and trimethylsilyl enol ethers.

BASE-INDUCED REARRANGEMENT OF 1-(TRIMETHYLSILYL)ALLYLIC ALCOHOLS. STEREO- AND REGIOSELECTIVE SYNTHESIS OF SILYL ENOL ETHERS THROUGH LITHIUM HOMOENOLATES.

1-(Trimethylsilyl)allylic alcohols have been prepared and their conversions to silyl enol ethers have been examined. Under appropriate conditions, lithium alkoxides of the above alcohols are in equilibrium with lithium homoenolates, 3-(trimethylsiloxy)allyllithiums, which react with alkyl iodides to give the silyl enol ethers of defined stereo- and regiochemistry. Further, a catalytic amount of butyllithium induces the rearrangement of the alcohols to yield the corresponding silyl enol ethers in a highly stereo- and regiocontrolled manner via self-protolysis. Equilibrium composition between lithium alkoxides and lithium homoenolates has been shown to be greatly influenced by the steric factors around alpha carbons of allylic alcohols.