7044-92-0Relevant articles and documents
Preparation method of 2, 5-disubstituted-1, 4-terephthalaldehyde
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Paragraph 0029-0031; 0038-0051, (2021/03/24)
The invention belongs to the technical field of organic synthesis, and particularly relates to a preparation method of 2, 5-disubstituted-1, 4-terephthalaldehyde The 2, 5-disubstituted-1, 4-terephthalaldehyde disclosed by the invention is prepared by carrying out oxidation reaction on 2, 5-disubstituted-1, 4-dibromobenzene and DMF under the catalytic action of hexamethylphosphoramide (HMPA) and tert-butyl lithium. According to the method, tert-butyl lithium is added into a reaction system, so that the reaction activity is greatly improved, the reaction yield is greatly improved and is 78% or above under the combined action of tert-butyl lithium and HMPA by virtue of a trace amount of HMPA and the existence form of stabilized carbocations, and the product quantification efficiency is greatly improved.
A Novel Strategy for the Construction of Covalent Organic Frameworks from Nonporous Covalent Organic Polymers
Miao, Zhuang,Liu, Guiyan,Cui, Yumeng,Liu, Zhengyu,Li, Jinheng,Han, Fangwai,Liu, Yu,Sun, Xiaoxiao,Gong, Xuefang,Zhai, Yufeng,Zhao, Yanli,Zeng, Yongfei
supporting information, p. 4906 - 4910 (2019/03/11)
The field of covalent organic frameworks (COFs) has been developed significantly in the past decade on account of their important characteristics and vast application potential. On the other hand, the discovery of novel synthetic methodology is still a ch
Attempted [2]Catenane Synthesis via a Quasi[1]catenane by a Templated Backfolding Strategy
Steemers, Luuk,Wanner, Martin J.,van Leeuwen, Bart R. C.,Hiemstra, Henk,van Maarseveen, Jan H.
supporting information, p. 874 - 878 (2018/02/27)
A templated backfolding concept to construct a [2]catenane was attempted via a quasi[1]catenane showing an inverted spiro geometry. The template is covalently connected to the ketal-connected semi-perpendicular-arranged linear precursors and spatially directs the sterically congested backfolding macrocyclizations that are required to give a quasi[1]catenane. So far, we are unable to hydrolyze the cyclic ketal to liberate the [2]catenane.