7046-64-2Relevant articles and documents
Preparation method of flame retardant for inflammable hazardous chemical plastic products
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Paragraph 0017; 0098-0101, (2017/09/28)
The invention discloses a preparation method of a flame retardant for inflammable hazardous chemical plastic products. The method includes the steps of: 1) in an aliphatic-series halogenated solvent, dissolving phenol, performing a dropwise-adding reaction under stirring with bromine, slowly increasing the temperature until the boiling range of the solvent, and performing reflux to prepare a dibromo (tribromo) phenol aliphatic-series halogenated solution; 2) slowly dropwise adding a newly distilled industrial product phosphorus oxychloride, and slowly dropwise adding diluted triethylamine into the reaction bottle, and then slowly increasing the temperature so as to perform a reaction to the solvent at boiling temperature; 3) maintaining stable reflux to prepare tri(2,4-dibromophenyl) phosphate or tri(2,4,6-tribromophenyl) phosphate; and 4) water-washing and re-crystallizing the product to obtain the flame retardant. The flame retardant is toxic-free, is low in melt point, has good thermostability and compatibility, is good in flame retarding effect, and can be widely used in engineering plastics and alloys, such as nitro-cotton, celluloid and the like.
TRIS(2,4,6-TRIBROMOPHENOXY)DICHLOROPHOSPHORANE: A NOVEL CONDENSING AGENT FOR RAPID INTERNUCLEOTID BOND FORMATION IN THE PHOSPHOTRIESTER APPROACH
Hotoda, Hitoshi,Wada, Takeshi,Sekine, Mitsuo,Hata, Tsujiaki
, p. 1681 - 1684 (2007/10/02)
A new class of condensing agent, Tris(2,4,6-tribromophenoxy)-dichlorophosphorane (BDCP), was applied to the oligodeoxyribonucleotide synthesis.This reagent enabled us to perform a rapid internucleotidic bond formation in the phosphotriester approach only