70471-02-2

Basic information

• Product Name: L-Glutamic acid, N-(phenylmethylene)-, dimethyl ester
• CAS NO: 70471-02-2
• Molecular Formula: C14H17NO4
• Molecular Weight: 263.293
• Mol File: 70471-02-2.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: L-Glutamic acid, N-(phenylmethylene)-, dimethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: L-Glutamic acid, N-(phenylmethylene)-, dimethyl ester(70471-02-2)
• EPA Substance Registry System: L-Glutamic acid, N-(phenylmethylene)-, dimethyl ester(70471-02-2)

Safety Data

• Hazardous Substances Data: 70471-02-2(Hazardous Substances Data)

Upstream product

• 23150-65-4 dimethyl glutamate hydrochloride 
• 100-52-7 benzaldehyde 
• 66646-88-6 (E)-N-benzylideneglycine methyl ester 
• 292638-85-8 acrylic acid methyl ester 
• 6525-53-7 glutamic acid dimethyl ether 

Downstream Products

• 95755-26-3 2-Difluoromethyl-2-{[1-phenyl-meth-(E)-ylidene]-amino}-pentanedioic acid dimethyl ester 
• 95755-28-5 2-Difluoromethyl-5-oxo-pyrrolidine-2-carboxylic acid 
• 102841-29-2 2-Difluoromethyl-2-(4-methylamino-benzoylamino)-pentanedioic acid dimethyl ester 
• 102841-31-6 2-[4-(Benzyloxycarbonyl-methyl-amino)-benzoylamino]-2-difluoromethyl-pentanedioic acid dimethyl ester 
• 95755-21-8 N-<4-<<(2,4-diamino-6-pteridinyl)methyl>methylamino>benzoyl>-2-difluoromethyl-glutamic acid 
• 102841-30-5 2-{4-[(2,4-Diamino-pteridin-6-ylmethyl)-methyl-amino]-benzoylamino}-2-difluoromethyl-pentanedioic acid dimethyl ester 

Relevant articles and documents

Stereoselective synthesis of functional derivatives of 2-(2-carboxyethyl) pyrrolidine-2-carboxylic acid

Azomethine ylides generated from dimethyl 2-(arylmethylideneamino) pentanedioates by the action of AgOAc and Et3N reacted with dipolarophiles in regio- and stereoselective fashion to form 5-aryl-2-(2-carboxyethyl)pyrrolidine-2-carboxylic acid derivatives. 1,3-Dipolar cycloaddition of divinyl sulfone to the azomethine ylide generated from the Schiff base derived from methyl (S)-2-phthalimido-4-oxobutanoate and dimethyl glutamate gave chiral simplified kaitocephalin analogs. Pleiades Publishing, Inc., 2006.

5-Endo-Trig Cyclisation and 1,3-Anionic Cycloaddition in Arylimine Derivatives of α-Amino Acid Esters

Michael adducts of imines of α-amino acid esters are converted into a mixture of two stereoisomeric pyrrolidines by benzyltrimethylammonium methoxide (BTAM) apparently by a 5-endo-trig cyclisation.