70729-31-6Relevant articles and documents
Investigation of the Organocatalytic Chlorination of 2-Phenylpropanal
Mohr, Lisa-Marie,McCulley, Christina H.,Blom, Jakob,Lamhauge, Johannes N.,Anker J?rgensen, Karl
supporting information, p. 17465 - 17475 (2021/10/25)
Results of an examination of the organocatalytic enantioselective α-chlorination of 2-phenylpropanal are described. Synthetic investigation including the screening of primary and secondary aminocatalysts, many different reaction conditions, and other α-br
The Rabe amination after a century: Direct addition of N-heterocycles to carbonyl compounds
Scarpino Schietroma, Daniele M.,Monaco, Mattia R.,Bucalossi, Valerio,Walter, Philipp E.,Gentili, Patrizia,Bella, Marco
scheme or table, p. 4692 - 4695 (2012/08/08)
A catalytic version of the Rabe electrophilic amination is presented. This kind of reaction was originally employed in 1918 in a key step for the conversion of quinotoxine to quinine. Ketones and α-substituted aldehydes give the corresponding α-aminated carbonyl compounds in moderate yield. α,α-Unsubstituted aldehydes give rise to amino ketones via a novel rearrangement.
Polymer-supported 4-(phenylseleno)morpholine as a useful α-selenenylating agent for saturated aldehydes. A highly efficient route to α-haloaldehydes on solid phase
Sheng, Shou-Ri,Huang, Xian
, p. 383 - 387 (2007/10/03)
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