70813-22-8Relevant articles and documents
Iron-catalyzed alkenylation of Grignard reagents by enol phosphates
Cahiez, Gerard,Gager, Olivier,Habiak, Vanessa
experimental part, p. 2636 - 2644 (2009/04/07)
Stereoselective preparation of trisubstituted olefins can be easily performed from an Z/E-mixture of enol phosphates by reacting only the E-isomer with a Grignard reagent in the presence of Fe(acac)3. This procedure combines a kinetic differentiation and a stereoselective reaction. The coupling is very chemoselective in the presence of an alkyl chloride, an ester, a ketone or a nitrile. Georg Thieme Verlag Stuttgart.