70975-34-7Relevant articles and documents
N -Trifluoromethylthiolated Sulfoximines
Bohnen, Christian,Bolm, Carsten
, p. 3011 - 3013 (2015)
Air- and moisture-stable N-trifluoromethylthio sulfoximines have been prepared from N-H-sulfoximines via the corresponding N-Br derivatives in excellent yields. The two-step process starts with an easy-to-perform bromination at the sulfoximine nitrogen, followed by a reaction with silver trifluoromethanethiolate. A one-pot reaction sequence allows difficult to prepare products to be obtained.
Homolytic Reaction of N-Halogenosulphoximides with Olefins and Toluene
Akasaka, Takeshi,Furukawa, Naomichi,Oae, Shigeru
, p. 1257 - 1261 (2007/10/02)
Homolytic addition reaction of N-halogenosulphoximides, i.e. diphenyl-N-chlorosulphoximide (1), diphenyl-N-bromosulphoximide (2), and methylphenyl-N-chlorosulphoximide (3), to olefins such as t-butylethylene and cyclohexene under both u.v. irradiation and thermolysis in the presence of a radical initiator was found to afford the corresponding N-alkylated sulphoximides, which are presumed to be formed via the initial addition of the sulphoximidoyl radical.Meanwhile, homolytic bromination of toluene with N-bromosulphoximide (2) proceeded readily by u.v. irradiation, or by thermal reaction in the presence of a radical initiator, to afford benzyl bromide.However, chlorination of toluene was sluggish with N-chlorosulphoximides (1) and (3). α-Bromination was interpreted in terms of a chain process involving bromine molecules like the 'Goldfinger mechanism', but not via that involving the sulphoximidoyl radical.