71067-27-1

Basic information

• Product Name: Butanediamide, N,N'-bis(phenylmethyl)-
• CAS NO: 71067-27-1
• Molecular Formula: C18H20N2O2
• Molecular Weight: 296.369
• Mol File: 71067-27-1.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: Butanediamide, N,N'-bis(phenylmethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Butanediamide, N,N'-bis(phenylmethyl)-(71067-27-1)
• EPA Substance Registry System: Butanediamide, N,N'-bis(phenylmethyl)-(71067-27-1)

Safety Data

• Hazardous Substances Data: 71067-27-1(Hazardous Substances Data)

Upstream product

• 123-56-8 Succinimide 
• 100-46-9 benzylamine 
• 543-20-4 succinoyl dichloride 
• 3859-41-4 1,3-cyclopentadione 
• 110-15-6 succinic acid 
• 6066-82-6 1-hydroxy-pyrrolidine-2,5-dione 
• 21994-93-4 N-Succinimidoxycarbonyl-β-alanin-ethylester 
• 106-65-0 Dimethyl succinate 
• 123-25-1 succinic acid diethyl ester 
• 638-32-4 succinamic acid 
• 4107-62-4 3-cyano-propionic acid methyl ester 

Relevant articles and documents

Cleavage of 1,3-dicarbonyls through oxidative amidation

A mild and convenient protocol for the oxidative cleavage of 1,3-diketone compounds is described. Under metal-free conditions, the method converts the 1,3-dicarbonyls into amides when treated with (nBu4N)N3 and iodine in the presence of an amine at room temperature. Using this method, a range of 1,3-dicarbonyls with various structural motifs including sterically demanding substituents and ordinary functional groups were easily fragmented, and it is demonstrated that cyclic 1,3-dicarbonyls can be directly transformed into acyclic diamides through ring-opening. Initial mechanistic studies show that diazidation of the enol form is followed by nucleophilic substitution with the amine.

Microwave-assisted preparation of amides using a stable and reusable mesoporous carbonaceous solid acid

An efficient and green microwave assisted protocol to prepare amides from amines via N-acylation using acidic polysaccharide derived mesoporous materials provides quantitative yields of amides in short reaction times.

Reactions of amines with N-hydroxy-, N-(2,3-epoxypropoxy)succinimide and naphthalimide

N-Hydroxynaphthalimide (1) and N-hydroxysuccinimide (2) have been prepared. 1 is stable towards alkali, while 2 undergoes hydrolysis at room temperature in the presence of alkali. 1 reacts with amines to form only the salts while 2 reacts with an equivalent amount of primary aliphatic amine to form monoamide of succinamic acid and with an excess of a primary aliphatic amine it forms diamide of succinic acid.It reacts with an aromatic primary amine, irrespective of its concentration, to form only the mono amide of succinamic acid.N-(2,3-Epoxypropoxy)naphthalimide (9) and -succinimide (13) have been prepared from 1 and 2, respectively. 9 on reaction with amines form N-(3-amino-2-hydroxypropoxy)naphthalimides (10). 13 reacts with secondary amines to form 1,3-bisamino-2-propanol, while with aniline it forms N-(3-phenylamino-2-hydroxypropoxy)succinimide.